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Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer

In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degrad...

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Detalles Bibliográficos
Autores principales: Xiao, Qiang, Cao, Yanjun, Zheng, Wenyu, Hou, Tianle, Gao, Shuhang, Lyu, Jianhua, Xiao, Hui, Chen, Yuzhu, Chen, Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9886932/
https://www.ncbi.nlm.nih.gov/pubmed/36717733
http://dx.doi.org/10.1038/s41598-023-28787-7
Descripción
Sumario:In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degradative characteristics and the surface morphology of RL before and after modification. The result indicated that FUP can significantly improve the performance of RL. The drying time of the LF is significantly shortened, the gloss, the pencil hardness, and the impact performance are significantly enhanced at the same time. TG analysis and thermal decomposition kinetics analysis illustrated that the thermal stability and the activation energy of LF2 were stronger than that of RL. In addition, SEM analysis illustrated that the surface smoothness of RL were also improved.