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Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degrad...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9886932/ https://www.ncbi.nlm.nih.gov/pubmed/36717733 http://dx.doi.org/10.1038/s41598-023-28787-7 |
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author | Xiao, Qiang Cao, Yanjun Zheng, Wenyu Hou, Tianle Gao, Shuhang Lyu, Jianhua Xiao, Hui Chen, Yuzhu Chen, Ming |
author_facet | Xiao, Qiang Cao, Yanjun Zheng, Wenyu Hou, Tianle Gao, Shuhang Lyu, Jianhua Xiao, Hui Chen, Yuzhu Chen, Ming |
author_sort | Xiao, Qiang |
collection | PubMed |
description | In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degradative characteristics and the surface morphology of RL before and after modification. The result indicated that FUP can significantly improve the performance of RL. The drying time of the LF is significantly shortened, the gloss, the pencil hardness, and the impact performance are significantly enhanced at the same time. TG analysis and thermal decomposition kinetics analysis illustrated that the thermal stability and the activation energy of LF2 were stronger than that of RL. In addition, SEM analysis illustrated that the surface smoothness of RL were also improved. |
format | Online Article Text |
id | pubmed-9886932 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-98869322023-02-01 Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer Xiao, Qiang Cao, Yanjun Zheng, Wenyu Hou, Tianle Gao, Shuhang Lyu, Jianhua Xiao, Hui Chen, Yuzhu Chen, Ming Sci Rep Article In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degradative characteristics and the surface morphology of RL before and after modification. The result indicated that FUP can significantly improve the performance of RL. The drying time of the LF is significantly shortened, the gloss, the pencil hardness, and the impact performance are significantly enhanced at the same time. TG analysis and thermal decomposition kinetics analysis illustrated that the thermal stability and the activation energy of LF2 were stronger than that of RL. In addition, SEM analysis illustrated that the surface smoothness of RL were also improved. Nature Publishing Group UK 2023-01-30 /pmc/articles/PMC9886932/ /pubmed/36717733 http://dx.doi.org/10.1038/s41598-023-28787-7 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Xiao, Qiang Cao, Yanjun Zheng, Wenyu Hou, Tianle Gao, Shuhang Lyu, Jianhua Xiao, Hui Chen, Yuzhu Chen, Ming Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer |
title | Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer |
title_full | Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer |
title_fullStr | Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer |
title_full_unstemmed | Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer |
title_short | Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer |
title_sort | kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9886932/ https://www.ncbi.nlm.nih.gov/pubmed/36717733 http://dx.doi.org/10.1038/s41598-023-28787-7 |
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