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Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer

In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degrad...

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Autores principales: Xiao, Qiang, Cao, Yanjun, Zheng, Wenyu, Hou, Tianle, Gao, Shuhang, Lyu, Jianhua, Xiao, Hui, Chen, Yuzhu, Chen, Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9886932/
https://www.ncbi.nlm.nih.gov/pubmed/36717733
http://dx.doi.org/10.1038/s41598-023-28787-7
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author Xiao, Qiang
Cao, Yanjun
Zheng, Wenyu
Hou, Tianle
Gao, Shuhang
Lyu, Jianhua
Xiao, Hui
Chen, Yuzhu
Chen, Ming
author_facet Xiao, Qiang
Cao, Yanjun
Zheng, Wenyu
Hou, Tianle
Gao, Shuhang
Lyu, Jianhua
Xiao, Hui
Chen, Yuzhu
Chen, Ming
author_sort Xiao, Qiang
collection PubMed
description In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degradative characteristics and the surface morphology of RL before and after modification. The result indicated that FUP can significantly improve the performance of RL. The drying time of the LF is significantly shortened, the gloss, the pencil hardness, and the impact performance are significantly enhanced at the same time. TG analysis and thermal decomposition kinetics analysis illustrated that the thermal stability and the activation energy of LF2 were stronger than that of RL. In addition, SEM analysis illustrated that the surface smoothness of RL were also improved.
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spelling pubmed-98869322023-02-01 Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer Xiao, Qiang Cao, Yanjun Zheng, Wenyu Hou, Tianle Gao, Shuhang Lyu, Jianhua Xiao, Hui Chen, Yuzhu Chen, Ming Sci Rep Article In this study, formaldehyde-urea prepolymer (FUP) were synthesized, which were used to modify the raw lacquer (RL) and this composition named LF, while the basic properties of the RL were tested. Thermal gravimetric (TG) analysis and scanning electron microscopy (SEM) were used to analyze the degradative characteristics and the surface morphology of RL before and after modification. The result indicated that FUP can significantly improve the performance of RL. The drying time of the LF is significantly shortened, the gloss, the pencil hardness, and the impact performance are significantly enhanced at the same time. TG analysis and thermal decomposition kinetics analysis illustrated that the thermal stability and the activation energy of LF2 were stronger than that of RL. In addition, SEM analysis illustrated that the surface smoothness of RL were also improved. Nature Publishing Group UK 2023-01-30 /pmc/articles/PMC9886932/ /pubmed/36717733 http://dx.doi.org/10.1038/s41598-023-28787-7 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Xiao, Qiang
Cao, Yanjun
Zheng, Wenyu
Hou, Tianle
Gao, Shuhang
Lyu, Jianhua
Xiao, Hui
Chen, Yuzhu
Chen, Ming
Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
title Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
title_full Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
title_fullStr Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
title_full_unstemmed Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
title_short Kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
title_sort kinetics of thermal degradation of raw lacquer enhanced by formaldehyde urea prepolymer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9886932/
https://www.ncbi.nlm.nih.gov/pubmed/36717733
http://dx.doi.org/10.1038/s41598-023-28787-7
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