Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation

[Image: see text] Unlike metal-ornamented hybrid material and linear polymers, we invoked the growth of a biodegradable superstructured cross-linked polyamide-ester material. The material is thermally stable. The thiol-alkene photoclicked material acted as an efficient water remediator. The material...

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Autores principales: Kumar, Rajan, Davis, Elizabathe, Mazumdar, Pradyumna, Choudhury, Diganta, Shunmugam, Raja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9888625/
https://www.ncbi.nlm.nih.gov/pubmed/36855766
http://dx.doi.org/10.1021/acsmaterialsau.1c00042
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author Kumar, Rajan
Davis, Elizabathe
Mazumdar, Pradyumna
Choudhury, Diganta
Shunmugam, Raja
author_facet Kumar, Rajan
Davis, Elizabathe
Mazumdar, Pradyumna
Choudhury, Diganta
Shunmugam, Raja
author_sort Kumar, Rajan
collection PubMed
description [Image: see text] Unlike metal-ornamented hybrid material and linear polymers, we invoked the growth of a biodegradable superstructured cross-linked polyamide-ester material. The material is thermally stable. The thiol-alkene photoclicked material acted as an efficient water remediator. The material efficiently monitored amphiphilic dyes like rhodamine B (RHB), methylene blue (MB), and chronic mercuric ions in water. The adsorption kinetics revealed the material could adsorb >95% dyes within 24 h. The RHB-functionalized polymer could sense mercuric ions too. The Density functional theory (DFT) calculation shows a chelated mercury complex with thioether in the polymer, Poly-Am-RhAll, to form a comparatively more stable complex.
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spelling pubmed-98886252023-02-27 Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation Kumar, Rajan Davis, Elizabathe Mazumdar, Pradyumna Choudhury, Diganta Shunmugam, Raja ACS Mater Au [Image: see text] Unlike metal-ornamented hybrid material and linear polymers, we invoked the growth of a biodegradable superstructured cross-linked polyamide-ester material. The material is thermally stable. The thiol-alkene photoclicked material acted as an efficient water remediator. The material efficiently monitored amphiphilic dyes like rhodamine B (RHB), methylene blue (MB), and chronic mercuric ions in water. The adsorption kinetics revealed the material could adsorb >95% dyes within 24 h. The RHB-functionalized polymer could sense mercuric ions too. The Density functional theory (DFT) calculation shows a chelated mercury complex with thioether in the polymer, Poly-Am-RhAll, to form a comparatively more stable complex. American Chemical Society 2021-11-08 /pmc/articles/PMC9888625/ /pubmed/36855766 http://dx.doi.org/10.1021/acsmaterialsau.1c00042 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Kumar, Rajan
Davis, Elizabathe
Mazumdar, Pradyumna
Choudhury, Diganta
Shunmugam, Raja
Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation
title Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation
title_full Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation
title_fullStr Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation
title_full_unstemmed Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation
title_short Engineering Spherically Super-Structured Polyamides for the Sustainable Water Remediation
title_sort engineering spherically super-structured polyamides for the sustainable water remediation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9888625/
https://www.ncbi.nlm.nih.gov/pubmed/36855766
http://dx.doi.org/10.1021/acsmaterialsau.1c00042
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