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Statistical copolymer metal organic nanotubes
Metal–organic nanotubes (MONTs) are 1-dimensional crystalline porous materials that are formed from ligands and metals in a manner identical to more typical 3-dimensional metal–organic frameworks (MOFs). MONTs form anisotropically in one dimension making them excellent candidates for linker engineer...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890963/ https://www.ncbi.nlm.nih.gov/pubmed/36755710 http://dx.doi.org/10.1039/d2sc06084a |
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author | Barrett, Jacob A. Rosenmann, Nathan D. Gnanasekaran, Karthikeyan Carroll, Xian B. Gianneschi, Nathan C. Jenkins, David M. |
author_facet | Barrett, Jacob A. Rosenmann, Nathan D. Gnanasekaran, Karthikeyan Carroll, Xian B. Gianneschi, Nathan C. Jenkins, David M. |
author_sort | Barrett, Jacob A. |
collection | PubMed |
description | Metal–organic nanotubes (MONTs) are 1-dimensional crystalline porous materials that are formed from ligands and metals in a manner identical to more typical 3-dimensional metal–organic frameworks (MOFs). MONTs form anisotropically in one dimension making them excellent candidates for linker engineering for control of chemical composition and spacing. A novel series of MONTs was synthesized utilizing a mixture of 1,2,4-ditriazole ligands containing both a fully protonated aryl moiety and its tetrafluorinated analog in ratios of, 0 : 1, 1 : 4, 1 : 1, 4 : 1, and 1 : 0, respectively. All MONTs were characterized by both bulk and nanoscale measurements, including SCXRD, PXRD, ssNMR and TEM, to determine the resulting co-polymer architecture (alternating, block, or statistical) and the ligand ratios in the solid materials. All characterization methods point towards statistical copolymerization of the materials in a manner analogous to 3D MOFs, all of which notably could be achieved without destructive analytical methods. |
format | Online Article Text |
id | pubmed-9890963 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-98909632023-02-07 Statistical copolymer metal organic nanotubes Barrett, Jacob A. Rosenmann, Nathan D. Gnanasekaran, Karthikeyan Carroll, Xian B. Gianneschi, Nathan C. Jenkins, David M. Chem Sci Chemistry Metal–organic nanotubes (MONTs) are 1-dimensional crystalline porous materials that are formed from ligands and metals in a manner identical to more typical 3-dimensional metal–organic frameworks (MOFs). MONTs form anisotropically in one dimension making them excellent candidates for linker engineering for control of chemical composition and spacing. A novel series of MONTs was synthesized utilizing a mixture of 1,2,4-ditriazole ligands containing both a fully protonated aryl moiety and its tetrafluorinated analog in ratios of, 0 : 1, 1 : 4, 1 : 1, 4 : 1, and 1 : 0, respectively. All MONTs were characterized by both bulk and nanoscale measurements, including SCXRD, PXRD, ssNMR and TEM, to determine the resulting co-polymer architecture (alternating, block, or statistical) and the ligand ratios in the solid materials. All characterization methods point towards statistical copolymerization of the materials in a manner analogous to 3D MOFs, all of which notably could be achieved without destructive analytical methods. The Royal Society of Chemistry 2023-01-06 /pmc/articles/PMC9890963/ /pubmed/36755710 http://dx.doi.org/10.1039/d2sc06084a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Barrett, Jacob A. Rosenmann, Nathan D. Gnanasekaran, Karthikeyan Carroll, Xian B. Gianneschi, Nathan C. Jenkins, David M. Statistical copolymer metal organic nanotubes |
title | Statistical copolymer metal organic nanotubes |
title_full | Statistical copolymer metal organic nanotubes |
title_fullStr | Statistical copolymer metal organic nanotubes |
title_full_unstemmed | Statistical copolymer metal organic nanotubes |
title_short | Statistical copolymer metal organic nanotubes |
title_sort | statistical copolymer metal organic nanotubes |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890963/ https://www.ncbi.nlm.nih.gov/pubmed/36755710 http://dx.doi.org/10.1039/d2sc06084a |
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