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An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes
The multistep chemical modification of carboxymethylcellulose (CMC) in the presence of 4-aminophenazone (A-PH) and multiwall carbon nanotubes (MWCNTs) has been successfully conducted. The environmental performance of this material has been thoroughly investigated. Crystal violet (CV) and brilliant g...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891083/ https://www.ncbi.nlm.nih.gov/pubmed/36760307 http://dx.doi.org/10.1039/d2ra07321h |
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author | Althomali, Raed H. Alamry, Khalid A. Hussein, Mahmoud A. Guedes, R. M. |
author_facet | Althomali, Raed H. Alamry, Khalid A. Hussein, Mahmoud A. Guedes, R. M. |
author_sort | Althomali, Raed H. |
collection | PubMed |
description | The multistep chemical modification of carboxymethylcellulose (CMC) in the presence of 4-aminophenazone (A-PH) and multiwall carbon nanotubes (MWCNTs) has been successfully conducted. The environmental performance of this material has been thoroughly investigated. Crystal violet (CV) and brilliant green (BG) were eliminated by utilising a new hybrid nanocomposite material (A-PH-CMC/MWCNTs) from a simulated textile wastewater solution. Using SEM, EDX, XRD and FTIR spectroscopy methods, the detailed characterisation of A-PH-CMC/MWCNT nanocomposites was investigated. The results indicated that the adsorption capacity was dependent on six factors (e.g., contact duration, starting concentration, adsorbent mass, the effect of the solution pH, temperature and the effect of KNO(3)). In addition, thermodynamic and regeneration studies have been reported. According to the theories of pseudo-second-order kinetics, the removal process involves chemical adsorption. The experimental results were best suited by the Langmuir model, in which maximum adsorption capacities of 20.83 and 22.42 mg g(−1) were predicted for the BG and CV dyes, respectively. The research is a preliminary case study demonstrating the excellent potential of A-PH-CMC/MWCNT nanocomposites as a material for CV and BG dye removal. |
format | Online Article Text |
id | pubmed-9891083 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-98910832023-02-08 An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes Althomali, Raed H. Alamry, Khalid A. Hussein, Mahmoud A. Guedes, R. M. RSC Adv Chemistry The multistep chemical modification of carboxymethylcellulose (CMC) in the presence of 4-aminophenazone (A-PH) and multiwall carbon nanotubes (MWCNTs) has been successfully conducted. The environmental performance of this material has been thoroughly investigated. Crystal violet (CV) and brilliant green (BG) were eliminated by utilising a new hybrid nanocomposite material (A-PH-CMC/MWCNTs) from a simulated textile wastewater solution. Using SEM, EDX, XRD and FTIR spectroscopy methods, the detailed characterisation of A-PH-CMC/MWCNT nanocomposites was investigated. The results indicated that the adsorption capacity was dependent on six factors (e.g., contact duration, starting concentration, adsorbent mass, the effect of the solution pH, temperature and the effect of KNO(3)). In addition, thermodynamic and regeneration studies have been reported. According to the theories of pseudo-second-order kinetics, the removal process involves chemical adsorption. The experimental results were best suited by the Langmuir model, in which maximum adsorption capacities of 20.83 and 22.42 mg g(−1) were predicted for the BG and CV dyes, respectively. The research is a preliminary case study demonstrating the excellent potential of A-PH-CMC/MWCNT nanocomposites as a material for CV and BG dye removal. The Royal Society of Chemistry 2023-01-31 /pmc/articles/PMC9891083/ /pubmed/36760307 http://dx.doi.org/10.1039/d2ra07321h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Althomali, Raed H. Alamry, Khalid A. Hussein, Mahmoud A. Guedes, R. M. An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes |
title | An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes |
title_full | An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes |
title_fullStr | An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes |
title_full_unstemmed | An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes |
title_short | An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes |
title_sort | investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@mwcnt nanocomposite against crystal violet and brilliant green dyes |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891083/ https://www.ncbi.nlm.nih.gov/pubmed/36760307 http://dx.doi.org/10.1039/d2ra07321h |
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