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Reactivity and Structure of a Bis-phenolate Niobium NHC Complex
[Image: see text] We report the facile synthesis of a rare niobium(V) imido NHC complex with a dianionic OCO-pincer benzimidazolylidene ligand (L(1)) with the general formula [NbL(1)(N(t)Bu)PyCl] 1-Py. We achieved this by in situ deprotonation of the corresponding azolium salt [H(3)L(1)][Cl] and sub...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9896488/ https://www.ncbi.nlm.nih.gov/pubmed/36748079 http://dx.doi.org/10.1021/acsorginorgau.2c00028 |