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Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field
While the dynamics of dimers and polymer chains in a viscous solvent is well understood within the celebrated Rouse model, the effect of an external magnetic field on the dynamics of a charged chain is much less understood. Here, we generalize the Rouse model for a charged dimer to include the effec...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Oxford University Press
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9896929/ https://www.ncbi.nlm.nih.gov/pubmed/36741452 http://dx.doi.org/10.1093/pnasnexus/pgac119 |
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author | Shinde, Rushikesh Sommer, Jens Uwe Löwen, Hartmut Sharma, Abhinav |
author_facet | Shinde, Rushikesh Sommer, Jens Uwe Löwen, Hartmut Sharma, Abhinav |
author_sort | Shinde, Rushikesh |
collection | PubMed |
description | While the dynamics of dimers and polymer chains in a viscous solvent is well understood within the celebrated Rouse model, the effect of an external magnetic field on the dynamics of a charged chain is much less understood. Here, we generalize the Rouse model for a charged dimer to include the effect of an external magnetic field. Our analytically solvable model allows a fundamental insight into the magneto-generated dynamics of the dimer in the overdamped limit as induced by the Lorentz force. Surprisingly, for a dimer of oppositely charged particles, we find an enormous enhancement of the dynamics of the dimer center, which exhibits even a transient superballistic behavior. This is highly unusual in an overdamped system for there is neither inertia nor any internal or external driving. We attribute this to a significant translation and rotation coupling due to the Lorentz force. We also find that magnetic field reduces the mobility of a dimer along its orientation and its effective rotational diffusion coefficient. In principle, our predictions can be tested by experiments with colloidal particles and complex plasmas. |
format | Online Article Text |
id | pubmed-9896929 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | Oxford University Press |
record_format | MEDLINE/PubMed |
spelling | pubmed-98969292023-02-04 Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field Shinde, Rushikesh Sommer, Jens Uwe Löwen, Hartmut Sharma, Abhinav PNAS Nexus Physical Sciences and Engineering While the dynamics of dimers and polymer chains in a viscous solvent is well understood within the celebrated Rouse model, the effect of an external magnetic field on the dynamics of a charged chain is much less understood. Here, we generalize the Rouse model for a charged dimer to include the effect of an external magnetic field. Our analytically solvable model allows a fundamental insight into the magneto-generated dynamics of the dimer in the overdamped limit as induced by the Lorentz force. Surprisingly, for a dimer of oppositely charged particles, we find an enormous enhancement of the dynamics of the dimer center, which exhibits even a transient superballistic behavior. This is highly unusual in an overdamped system for there is neither inertia nor any internal or external driving. We attribute this to a significant translation and rotation coupling due to the Lorentz force. We also find that magnetic field reduces the mobility of a dimer along its orientation and its effective rotational diffusion coefficient. In principle, our predictions can be tested by experiments with colloidal particles and complex plasmas. Oxford University Press 2022-07-23 /pmc/articles/PMC9896929/ /pubmed/36741452 http://dx.doi.org/10.1093/pnasnexus/pgac119 Text en © The Author(s) 2022. Published by Oxford University Press on behalf of the National Academy of Sciences. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Physical Sciences and Engineering Shinde, Rushikesh Sommer, Jens Uwe Löwen, Hartmut Sharma, Abhinav Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field |
title | Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field |
title_full | Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field |
title_fullStr | Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field |
title_full_unstemmed | Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field |
title_short | Strongly enhanced dynamics of a charged Rouse dimer by an external magnetic field |
title_sort | strongly enhanced dynamics of a charged rouse dimer by an external magnetic field |
topic | Physical Sciences and Engineering |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9896929/ https://www.ncbi.nlm.nih.gov/pubmed/36741452 http://dx.doi.org/10.1093/pnasnexus/pgac119 |
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