Transient Elastomers with High Dielectric Permittivity for Actuators, Sensors, and Beyond

[Image: see text] Dielectric elastomers (DEs) are key materials in actuators, sensors, energy harvesters, and stretchable electronics. These devices find applications in important emerging fields such as personalized medicine, renewable energy, and soft robotics. However, even after years of research, it is still a great challenge to achieve DEs with increased dielectric permittivity and fast recovery of initial shape when subjected to mechanical and electrical stress. Additionally, high dielectric permittivity elastomers that show reliable performance but disintegrate under normal environmental conditions are not known. Here, we show that polysiloxanes modified with amide groups give elastomers with a dielectric permittivity of 21, which is 7 times higher than regular silicone rubber, a strain at break that can reach 150%, and a mechanical loss factor tan δ below 0.05 at low frequencies. Actuators constructed from these elastomers respond to a low electric field of 6.2 V μm(–1), giving reliable lateral actuation of 4% for more than 30 000 cycles at 5 Hz. One survived 450 000 cycles at 10 Hz and 3.6 V μm(–1). The best actuator shows 10% lateral strain at 7.5 V μm(–1). Capacitive sensors offer a more than a 6-fold increase in sensitivity compared to standard silicone elastomers. The disintegrated material can be re-cross-linked when heated to elevated temperatures. In the future, our material could be used as dielectric in transient actuators, sensors, security devices, and disposable electronic patches for health monitoring.