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Post-synthesis of Sn-beta zeolite by aerosol method
Sn-beta zeolite is a Lewis acid catalyst which can activate the C–O and C[double bond, length as m-dash]O bonds of many organic compounds. In this paper, a simple aerosol method has been firstly applied to the post-synthesis of Sn-beta zeolite. The aqueous solution containing SnCl(2) and dealuminate...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9903300/ https://www.ncbi.nlm.nih.gov/pubmed/36760268 http://dx.doi.org/10.1039/d2ra06366b |
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author | Xiong, Guang Yang, Huaxiang Liu, Liping Liu, Jiaxu |
author_facet | Xiong, Guang Yang, Huaxiang Liu, Liping Liu, Jiaxu |
author_sort | Xiong, Guang |
collection | PubMed |
description | Sn-beta zeolite is a Lewis acid catalyst which can activate the C–O and C[double bond, length as m-dash]O bonds of many organic compounds. In this paper, a simple aerosol method has been firstly applied to the post-synthesis of Sn-beta zeolite. The aqueous solution containing SnCl(2) and dealuminated beta zeolite was rapidly dried using an aerosol generator to obtain the Sn-beta zeolites with different Sn contents. The physicochemical properties of the Sn-beta zeolites were further characterized by XRD, nitrogen adsorption–desorption, FT-IR and Py-FT-IR techniques. The catalysts exhibited good catalytic performances in the Baeyer–Villiger oxidation reaction of cyclohexanone. |
format | Online Article Text |
id | pubmed-9903300 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-99033002023-02-08 Post-synthesis of Sn-beta zeolite by aerosol method Xiong, Guang Yang, Huaxiang Liu, Liping Liu, Jiaxu RSC Adv Chemistry Sn-beta zeolite is a Lewis acid catalyst which can activate the C–O and C[double bond, length as m-dash]O bonds of many organic compounds. In this paper, a simple aerosol method has been firstly applied to the post-synthesis of Sn-beta zeolite. The aqueous solution containing SnCl(2) and dealuminated beta zeolite was rapidly dried using an aerosol generator to obtain the Sn-beta zeolites with different Sn contents. The physicochemical properties of the Sn-beta zeolites were further characterized by XRD, nitrogen adsorption–desorption, FT-IR and Py-FT-IR techniques. The catalysts exhibited good catalytic performances in the Baeyer–Villiger oxidation reaction of cyclohexanone. The Royal Society of Chemistry 2023-02-07 /pmc/articles/PMC9903300/ /pubmed/36760268 http://dx.doi.org/10.1039/d2ra06366b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Xiong, Guang Yang, Huaxiang Liu, Liping Liu, Jiaxu Post-synthesis of Sn-beta zeolite by aerosol method |
title | Post-synthesis of Sn-beta zeolite by aerosol method |
title_full | Post-synthesis of Sn-beta zeolite by aerosol method |
title_fullStr | Post-synthesis of Sn-beta zeolite by aerosol method |
title_full_unstemmed | Post-synthesis of Sn-beta zeolite by aerosol method |
title_short | Post-synthesis of Sn-beta zeolite by aerosol method |
title_sort | post-synthesis of sn-beta zeolite by aerosol method |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9903300/ https://www.ncbi.nlm.nih.gov/pubmed/36760268 http://dx.doi.org/10.1039/d2ra06366b |
work_keys_str_mv | AT xiongguang postsynthesisofsnbetazeolitebyaerosolmethod AT yanghuaxiang postsynthesisofsnbetazeolitebyaerosolmethod AT liuliping postsynthesisofsnbetazeolitebyaerosolmethod AT liujiaxu postsynthesisofsnbetazeolitebyaerosolmethod |