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Ru-Catalyzed Isomerization of Achmatowicz Derivatives: A Sustainable Route to Biorenewables and Bioactive Lactones
[Image: see text] A Ru-catalyzed isomerization of Achmatowicz derivatives that opens unexplored routes to diversify the biogenic furanic platform is reported. The mechanistic insights of this formally redox-neutral intramolecular process were studied computationally and by deuterium labeling. The tr...
Autores principales: | Dangalov, Miroslav, Fernández-Figueiras, Adolfo, Ravutsov, Martin A., Vakarelska, Ekaterina, Marinova, Maya K., Candeias, Nuno R., Simeonov, Svilen P. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9904008/ https://www.ncbi.nlm.nih.gov/pubmed/36776384 http://dx.doi.org/10.1021/acscatal.2c04867 |
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