Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions

[Image: see text] We report that the carborane-based metal–organic framework (MOF) mCB-MOF-1 can achieve high adsorptive selectivity for CO(2):N(2) mixtures. This hydrophobic MOF presenting open metal sites shows high CO(2) adsorption capacity and remarkable selectivity values that are maintained ev...

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Autores principales: Gan, Lei, Andres-Garcia, Eduardo, Mínguez Espallargas, Guillermo, Planas, José Giner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906620/
https://www.ncbi.nlm.nih.gov/pubmed/36691894
http://dx.doi.org/10.1021/acsami.2c20373
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author Gan, Lei
Andres-Garcia, Eduardo
Mínguez Espallargas, Guillermo
Planas, José Giner
author_facet Gan, Lei
Andres-Garcia, Eduardo
Mínguez Espallargas, Guillermo
Planas, José Giner
author_sort Gan, Lei
collection PubMed
description [Image: see text] We report that the carborane-based metal–organic framework (MOF) mCB-MOF-1 can achieve high adsorptive selectivity for CO(2):N(2) mixtures. This hydrophobic MOF presenting open metal sites shows high CO(2) adsorption capacity and remarkable selectivity values that are maintained even under extremely humid conditions. The comparison of mCB-MOF-1' with MOF-74(Ni) demonstrates the superior performance of the former under challenging moisture operation conditions.
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spelling pubmed-99066202023-02-08 Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions Gan, Lei Andres-Garcia, Eduardo Mínguez Espallargas, Guillermo Planas, José Giner ACS Appl Mater Interfaces [Image: see text] We report that the carborane-based metal–organic framework (MOF) mCB-MOF-1 can achieve high adsorptive selectivity for CO(2):N(2) mixtures. This hydrophobic MOF presenting open metal sites shows high CO(2) adsorption capacity and remarkable selectivity values that are maintained even under extremely humid conditions. The comparison of mCB-MOF-1' with MOF-74(Ni) demonstrates the superior performance of the former under challenging moisture operation conditions. American Chemical Society 2023-01-24 /pmc/articles/PMC9906620/ /pubmed/36691894 http://dx.doi.org/10.1021/acsami.2c20373 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Gan, Lei
Andres-Garcia, Eduardo
Mínguez Espallargas, Guillermo
Planas, José Giner
Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions
title Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions
title_full Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions
title_fullStr Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions
title_full_unstemmed Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions
title_short Adsorptive Separation of CO(2) by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions
title_sort adsorptive separation of co(2) by a hydrophobic carborane-based metal–organic framework under humid conditions
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906620/
https://www.ncbi.nlm.nih.gov/pubmed/36691894
http://dx.doi.org/10.1021/acsami.2c20373
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