Enhanced Thermoelectric Properties of a Semiconducting Two-Dimensional Metal–Organic Framework via Iodine Loading

[Image: see text] We report the first result of a study in which molecular iodine has been incorporated via incipient wetness impregnation into the two-dimensional semiconducting metal–organic framework (MOF) Cu(3)(2,3,6,7,10,11-hexahydroxytriphenylene)(2) Cu(3)(HHTP)(2) to enhance its thermoelectri...

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Detalles Bibliográficos
Autores principales: Gonzalez-Juarez, Maria de Lourdes, Isaacs, Mark A., Bradshaw, Darren, Nandhakumar, Iris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906625/
https://www.ncbi.nlm.nih.gov/pubmed/36688601
http://dx.doi.org/10.1021/acsami.2c20770
Descripción
Sumario:[Image: see text] We report the first result of a study in which molecular iodine has been incorporated via incipient wetness impregnation into the two-dimensional semiconducting metal–organic framework (MOF) Cu(3)(2,3,6,7,10,11-hexahydroxytriphenylene)(2) Cu(3)(HHTP)(2) to enhance its thermoelectric properties. A power factor of 0.757 μW m(–1) K(–2) for this MOF was obtained which demonstrates that this provides an effective route for the preparation of moderate-performance thermoelectric MOFs.

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