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Enantioselective Suzuki cross-coupling of 1,2-diboryl cyclopropanes

Herein, we describe the catalytic enantioselective cross-coupling of 1,2-bisboronic esters. Prior work on group specific cross coupling is limited to the use of geminal bis-boronates. This desymmetrization provides a novel approach to prepare enantioenriched cyclopropyl boronates with three contiguo...

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Detalles Bibliográficos
Autores principales: Teresa, Javier, Velado, Marina, Fernández de la Pradilla, Roberto, Viso, Alma, Lozano, Blanca, Tortosa, Mariola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906671/
https://www.ncbi.nlm.nih.gov/pubmed/36794195
http://dx.doi.org/10.1039/d2sc05789a