Cargando…
Advances in the Synthesis of Covalent Triazine Frameworks
[Image: see text] Covalent triazine frameworks (CTFs) are a class of organic polymer materials constructed by aromatic 1,3,5-triazine rings with planar π-conjugation properties. CTFs are highly stable and porous with N atoms in the frameworks, possessing semiconductive properties; thus they are wide...
Autores principales: | , , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9909813/ https://www.ncbi.nlm.nih.gov/pubmed/36777586 http://dx.doi.org/10.1021/acsomega.2c06961 |
_version_ | 1784884654983086080 |
---|---|
author | Liao, Longfei Li, Mingyu Yin, Yongli Chen, Jian Zhong, Qitong Du, Ruixing Liu, Shuilian He, Yiming Fu, Weijie Zeng, Feng |
author_facet | Liao, Longfei Li, Mingyu Yin, Yongli Chen, Jian Zhong, Qitong Du, Ruixing Liu, Shuilian He, Yiming Fu, Weijie Zeng, Feng |
author_sort | Liao, Longfei |
collection | PubMed |
description | [Image: see text] Covalent triazine frameworks (CTFs) are a class of organic polymer materials constructed by aromatic 1,3,5-triazine rings with planar π-conjugation properties. CTFs are highly stable and porous with N atoms in the frameworks, possessing semiconductive properties; thus they are widely used in gas adsorption and separation as well as catalysis. The properties of CTFs strongly depend on the type of monomers and the synthesis process. Synthesis methods including ionothermal polymerization, amino-aldehyde synthesis, trifluoromethanesulfonic acid catalyzed synthesis, and aldehyde–amidine condensation have been intensively studied in recent years. In this review, we discuss the recent advances and future developments of CTFs synthesis. |
format | Online Article Text |
id | pubmed-9909813 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-99098132023-02-10 Advances in the Synthesis of Covalent Triazine Frameworks Liao, Longfei Li, Mingyu Yin, Yongli Chen, Jian Zhong, Qitong Du, Ruixing Liu, Shuilian He, Yiming Fu, Weijie Zeng, Feng ACS Omega [Image: see text] Covalent triazine frameworks (CTFs) are a class of organic polymer materials constructed by aromatic 1,3,5-triazine rings with planar π-conjugation properties. CTFs are highly stable and porous with N atoms in the frameworks, possessing semiconductive properties; thus they are widely used in gas adsorption and separation as well as catalysis. The properties of CTFs strongly depend on the type of monomers and the synthesis process. Synthesis methods including ionothermal polymerization, amino-aldehyde synthesis, trifluoromethanesulfonic acid catalyzed synthesis, and aldehyde–amidine condensation have been intensively studied in recent years. In this review, we discuss the recent advances and future developments of CTFs synthesis. American Chemical Society 2023-01-23 /pmc/articles/PMC9909813/ /pubmed/36777586 http://dx.doi.org/10.1021/acsomega.2c06961 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Liao, Longfei Li, Mingyu Yin, Yongli Chen, Jian Zhong, Qitong Du, Ruixing Liu, Shuilian He, Yiming Fu, Weijie Zeng, Feng Advances in the Synthesis of Covalent Triazine Frameworks |
title | Advances in the Synthesis of Covalent Triazine Frameworks |
title_full | Advances in the Synthesis of Covalent Triazine Frameworks |
title_fullStr | Advances in the Synthesis of Covalent Triazine Frameworks |
title_full_unstemmed | Advances in the Synthesis of Covalent Triazine Frameworks |
title_short | Advances in the Synthesis of Covalent Triazine Frameworks |
title_sort | advances in the synthesis of covalent triazine frameworks |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9909813/ https://www.ncbi.nlm.nih.gov/pubmed/36777586 http://dx.doi.org/10.1021/acsomega.2c06961 |
work_keys_str_mv | AT liaolongfei advancesinthesynthesisofcovalenttriazineframeworks AT limingyu advancesinthesynthesisofcovalenttriazineframeworks AT yinyongli advancesinthesynthesisofcovalenttriazineframeworks AT chenjian advancesinthesynthesisofcovalenttriazineframeworks AT zhongqitong advancesinthesynthesisofcovalenttriazineframeworks AT duruixing advancesinthesynthesisofcovalenttriazineframeworks AT liushuilian advancesinthesynthesisofcovalenttriazineframeworks AT heyiming advancesinthesynthesisofcovalenttriazineframeworks AT fuweijie advancesinthesynthesisofcovalenttriazineframeworks AT zengfeng advancesinthesynthesisofcovalenttriazineframeworks |