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Electrical discharge triggers quasicrystal formation in an eolian dune

We report the discovery of a dodecagonal quasicrystal Mn(72.3)Si(15.6)Cr(9.7)Al(1.8)Ni(0.6)—composed of a periodic stacking of atomic planes with quasiperiodic translational order and 12-fold symmetry along the two directions perpendicular to the planes—accidentally formed by an electrical discharge...

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Detalles Bibliográficos
Autores principales: Bindi, Luca, Pasek, Matthew A., Ma, Chi, Hu, Jinping, Cheng, Guangming, Yao, Nan, Asimow, Paul D., Steinhardt, Paul J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9910441/
https://www.ncbi.nlm.nih.gov/pubmed/36574683
http://dx.doi.org/10.1073/pnas.2215484119
Descripción
Sumario:We report the discovery of a dodecagonal quasicrystal Mn(72.3)Si(15.6)Cr(9.7)Al(1.8)Ni(0.6)—composed of a periodic stacking of atomic planes with quasiperiodic translational order and 12-fold symmetry along the two directions perpendicular to the planes—accidentally formed by an electrical discharge event in an eolian dune in the Sand Hills near Hyannis, Nebraska, United States. The quasicrystal, coexisting with a cubic crystalline phase with composition Mn(68.9)Si(19.9)Ni(7.6)Cr(2.2)Al(1.4), was found in a fulgurite consisting predominantly of fused and melted sand along with traces of melted conductor metal from a nearby downed power line. The fulgurite may have been created by a lightning strike that combined sand with material from downed power line or from electrical discharges from the downed power line alone. Extreme temperatures of at least 1,710 °C were reached, as indicated by the presence of SiO(2) glass in the sample. The dodecagonal quasicrystal is an example of a quasicrystal of any kind formed by electrical discharge, suggesting other places to search for quasicrystals on Earth or in space and for synthesizing them in the laboratory.