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Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force

This study experimentally investigated the evaporation and wetting transition behavior of fakir droplets on five different microstructured surfaces. Diamond-like carbon was introduced as the substrate, and the influence of varying the width, height, and pitch of the micropillars was assessed. The ex...

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Autores principales: Shamim, Jubair A., Takahashi, Yukinari, Goswami, Anjan, Shaukat, Nadeem, Hsu, Wei-Lun, Choi, Junho, Daiguji, Hirofumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9911698/
https://www.ncbi.nlm.nih.gov/pubmed/36759577
http://dx.doi.org/10.1038/s41598-023-29163-1
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author Shamim, Jubair A.
Takahashi, Yukinari
Goswami, Anjan
Shaukat, Nadeem
Hsu, Wei-Lun
Choi, Junho
Daiguji, Hirofumi
author_facet Shamim, Jubair A.
Takahashi, Yukinari
Goswami, Anjan
Shaukat, Nadeem
Hsu, Wei-Lun
Choi, Junho
Daiguji, Hirofumi
author_sort Shamim, Jubair A.
collection PubMed
description This study experimentally investigated the evaporation and wetting transition behavior of fakir droplets on five different microstructured surfaces. Diamond-like carbon was introduced as the substrate, and the influence of varying the width, height, and pitch of the micropillars was assessed. The experimental results showed that the interfacial properties of the surfaces change the evaporation behavior and the starting point of the wetting transition. An important result of this study is the demonstration of a slippery superhydrophobic surface with low depinning force that suppresses the transition from the Cassie–Baxter state to the Wenzel state for microdroplets less than 0.37 mm in diameter, without employing large pillar height or multiscale roughness. By selecting an appropriate pillar pitch and employing tapered micropillars with small pillar widths, the solid–liquid contact at the three-phase contact line was reduced and low depinning forces were obtained. The underlying mechanism by which slippery superhydrophobic surfaces suppress wetting transitions is also discussed. The accuracy of the theoretical models for predicting the critical transition parameters was assessed, and a numerical model was developed in the surface evolver to compute the penetration of the droplet bottom meniscus within the micropillars.
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spelling pubmed-99116982023-02-11 Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force Shamim, Jubair A. Takahashi, Yukinari Goswami, Anjan Shaukat, Nadeem Hsu, Wei-Lun Choi, Junho Daiguji, Hirofumi Sci Rep Article This study experimentally investigated the evaporation and wetting transition behavior of fakir droplets on five different microstructured surfaces. Diamond-like carbon was introduced as the substrate, and the influence of varying the width, height, and pitch of the micropillars was assessed. The experimental results showed that the interfacial properties of the surfaces change the evaporation behavior and the starting point of the wetting transition. An important result of this study is the demonstration of a slippery superhydrophobic surface with low depinning force that suppresses the transition from the Cassie–Baxter state to the Wenzel state for microdroplets less than 0.37 mm in diameter, without employing large pillar height or multiscale roughness. By selecting an appropriate pillar pitch and employing tapered micropillars with small pillar widths, the solid–liquid contact at the three-phase contact line was reduced and low depinning forces were obtained. The underlying mechanism by which slippery superhydrophobic surfaces suppress wetting transitions is also discussed. The accuracy of the theoretical models for predicting the critical transition parameters was assessed, and a numerical model was developed in the surface evolver to compute the penetration of the droplet bottom meniscus within the micropillars. Nature Publishing Group UK 2023-02-09 /pmc/articles/PMC9911698/ /pubmed/36759577 http://dx.doi.org/10.1038/s41598-023-29163-1 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Shamim, Jubair A.
Takahashi, Yukinari
Goswami, Anjan
Shaukat, Nadeem
Hsu, Wei-Lun
Choi, Junho
Daiguji, Hirofumi
Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force
title Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force
title_full Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force
title_fullStr Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force
title_full_unstemmed Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force
title_short Suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force
title_sort suppression of wetting transition on evaporative fakir droplets by using slippery superhydrophobic surfaces with low depinning force
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9911698/
https://www.ncbi.nlm.nih.gov/pubmed/36759577
http://dx.doi.org/10.1038/s41598-023-29163-1
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