Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K

The structure of the dimeric title compound, [Sn(2)(C(4)H(9))(4)Cl(2)(OH)(2)], was redetermined at 100 K by use of an area detector to provide new data to improve the structural parameters for detailed analysis. Noteworthy is the folding of the central, non-symmetric, four-membered [SnO](2) ring [di...

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Autor principal: Reuter, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9912314/
https://www.ncbi.nlm.nih.gov/pubmed/36794054
http://dx.doi.org/10.1107/S2414314623000561
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author Reuter, Hans
author_facet Reuter, Hans
author_sort Reuter, Hans
collection PubMed
description The structure of the dimeric title compound, [Sn(2)(C(4)H(9))(4)Cl(2)(OH)(2)], was redetermined at 100 K by use of an area detector to provide new data to improve the structural parameters for detailed analysis. Noteworthy is the folding of the central, non-symmetric, four-membered [SnO](2) ring [dihedral angle about the O⋯O axis = 1.09 (3)°], as well as the elongation of the Sn—Cl bonds [mean value = 2.5096 (4) Å], as a result of inter­molecular O—H⋯Cl hydrogen bonds; the latter lead to a chain-like arrangement of dimeric mol­ecules along [101]. [Image: see text]
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spelling pubmed-99123142023-02-14 Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K Reuter, Hans IUCrdata Data Reports The structure of the dimeric title compound, [Sn(2)(C(4)H(9))(4)Cl(2)(OH)(2)], was redetermined at 100 K by use of an area detector to provide new data to improve the structural parameters for detailed analysis. Noteworthy is the folding of the central, non-symmetric, four-membered [SnO](2) ring [dihedral angle about the O⋯O axis = 1.09 (3)°], as well as the elongation of the Sn—Cl bonds [mean value = 2.5096 (4) Å], as a result of inter­molecular O—H⋯Cl hydrogen bonds; the latter lead to a chain-like arrangement of dimeric mol­ecules along [101]. [Image: see text] International Union of Crystallography 2023-01-26 /pmc/articles/PMC9912314/ /pubmed/36794054 http://dx.doi.org/10.1107/S2414314623000561 Text en © Hans Reuter 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Reuter, Hans
Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K
title Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K
title_full Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K
title_fullStr Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K
title_full_unstemmed Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K
title_short Redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(IV)] at 100 K
title_sort redetermination of the crystal structure of di-μ(2)-hydroxido-bis­[di-tert-butyl­chlorido­tin(iv)] at 100 k
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9912314/
https://www.ncbi.nlm.nih.gov/pubmed/36794054
http://dx.doi.org/10.1107/S2414314623000561
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