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Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane

[Image: see text] C–H/Et-Al exchange in zirconium-catalyzed reactions of saturated hydrocarbons and AlEt(3) affords versatile organoaluminum compounds and ethane. The grafting of commercially available Zr(OtBu)(4) on silica/alumina gives monopodal ≡SiO–Zr(OtBu)(3) surface pre-catalyst sites that are...

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Detalles Bibliográficos
Autores principales:	Kanbur, Uddhav, Paterson, Alexander L., Rodriguez, Jessica, Kocen, Andrew L., Yappert, Ryan, Hackler, Ryan A., Wang, Yi-Yu, Peters, Baron, Delferro, Massimiliano, LaPointe, Anne M., Coates, Geoffrey W., Perras, Frédéric A., Sadow, Aaron D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9912340/ https://www.ncbi.nlm.nih.gov/pubmed/36696148 http://dx.doi.org/10.1021/jacs.2c11056

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