Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV)

The title Sn(IV) complex, [Sn(C(6)H(5))(3)Cl(C(18)H(15)O(4)P)], is a formal adduct between triphenyl phosphate (PhO)(3)P=O and the stannane derivative chlorido­tri­phenyl­tin, SnPh(3)Cl. The structure refinement reveals that this mol­ecule displays the largest Sn—O bond length for compounds includin...

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Autores principales: Pouye, Serigne Fallou, Bernès, Sylvain, Yaffa, Lamine, Diallo, Waly, Cissé, Ibrahima, Diop, Cheikh Abdoul Khadir, Sidibé, Mamadou, Diop, Libasse
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9912461/
https://www.ncbi.nlm.nih.gov/pubmed/36793403
http://dx.doi.org/10.1107/S2056989023000270
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author Pouye, Serigne Fallou
Bernès, Sylvain
Yaffa, Lamine
Diallo, Waly
Cissé, Ibrahima
Diop, Cheikh Abdoul Khadir
Sidibé, Mamadou
Diop, Libasse
author_facet Pouye, Serigne Fallou
Bernès, Sylvain
Yaffa, Lamine
Diallo, Waly
Cissé, Ibrahima
Diop, Cheikh Abdoul Khadir
Sidibé, Mamadou
Diop, Libasse
author_sort Pouye, Serigne Fallou
collection PubMed
description The title Sn(IV) complex, [Sn(C(6)H(5))(3)Cl(C(18)H(15)O(4)P)], is a formal adduct between triphenyl phosphate (PhO)(3)P=O and the stannane derivative chlorido­tri­phenyl­tin, SnPh(3)Cl. The structure refinement reveals that this mol­ecule displays the largest Sn—O bond length for compounds including the X=O→SnPh(3)Cl fragment (X = P, S, C, or V), 2.6644 (17) Å. However, an AIM topology analysis based on the wavefunction calculated from the refined X-ray structure shows the presence of a bond critical point (3,−1), lying on the inter­basin surface separating the coordinated phosphate O atom and the Sn atom. This study thus shows that an actual polar covalent bond is formed between (PhO)(3)P=O and SnPh(3)Cl moieties.
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spelling pubmed-99124612023-02-14 Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV) Pouye, Serigne Fallou Bernès, Sylvain Yaffa, Lamine Diallo, Waly Cissé, Ibrahima Diop, Cheikh Abdoul Khadir Sidibé, Mamadou Diop, Libasse Acta Crystallogr E Crystallogr Commun Research Communications The title Sn(IV) complex, [Sn(C(6)H(5))(3)Cl(C(18)H(15)O(4)P)], is a formal adduct between triphenyl phosphate (PhO)(3)P=O and the stannane derivative chlorido­tri­phenyl­tin, SnPh(3)Cl. The structure refinement reveals that this mol­ecule displays the largest Sn—O bond length for compounds including the X=O→SnPh(3)Cl fragment (X = P, S, C, or V), 2.6644 (17) Å. However, an AIM topology analysis based on the wavefunction calculated from the refined X-ray structure shows the presence of a bond critical point (3,−1), lying on the inter­basin surface separating the coordinated phosphate O atom and the Sn atom. This study thus shows that an actual polar covalent bond is formed between (PhO)(3)P=O and SnPh(3)Cl moieties. International Union of Crystallography 2023-01-17 /pmc/articles/PMC9912461/ /pubmed/36793403 http://dx.doi.org/10.1107/S2056989023000270 Text en © Pouye et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Pouye, Serigne Fallou
Bernès, Sylvain
Yaffa, Lamine
Diallo, Waly
Cissé, Ibrahima
Diop, Cheikh Abdoul Khadir
Sidibé, Mamadou
Diop, Libasse
Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV)
title Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV)
title_full Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV)
title_fullStr Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV)
title_full_unstemmed Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV)
title_short Synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κO)tin(IV)
title_sort synthesis and topology analysis of chlorido­triphen­yl(triphenyl phosphate-κo)tin(iv)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9912461/
https://www.ncbi.nlm.nih.gov/pubmed/36793403
http://dx.doi.org/10.1107/S2056989023000270
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