Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3)

The orthophosphate BaNi(2)Fe(PO(4))(3) has been synthesized by a solid-state reaction route and characterized by single-crystal X-ray diffraction and energy-dispersive X-ray spectroscopy. The crystal structure comprises (100) sheets made up of [Ni(2)O(10)] dimers that are linked to two PO(4) tetra­h...

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Autores principales: Ouaatta, Said, Bouraima, Adam, Benhsina, Elhassan, Khmiyas, Jamal, Assani, Abderrazzak, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9912466/
https://www.ncbi.nlm.nih.gov/pubmed/36793405
http://dx.doi.org/10.1107/S2056989023000336
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author Ouaatta, Said
Bouraima, Adam
Benhsina, Elhassan
Khmiyas, Jamal
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_facet Ouaatta, Said
Bouraima, Adam
Benhsina, Elhassan
Khmiyas, Jamal
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_sort Ouaatta, Said
collection PubMed
description The orthophosphate BaNi(2)Fe(PO(4))(3) has been synthesized by a solid-state reaction route and characterized by single-crystal X-ray diffraction and energy-dispersive X-ray spectroscopy. The crystal structure comprises (100) sheets made up of [Ni(2)O(10)] dimers that are linked to two PO(4) tetra­hedra via common edges and vertices and of linear infinite [010] chains of corner-sharing [FeO(6)] octa­hedra and [PO(4)] tetra­hedra. The linkage of the sheets and chains into a framework is accomplished through common vertices of PO(4) tetra­hedra and [FeO(6)] octa­hedra. The framework is perforated by channels in which positionally disordered Ba(2+) cations are located.
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spelling pubmed-99124662023-02-14 Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3) Ouaatta, Said Bouraima, Adam Benhsina, Elhassan Khmiyas, Jamal Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Research Communications The orthophosphate BaNi(2)Fe(PO(4))(3) has been synthesized by a solid-state reaction route and characterized by single-crystal X-ray diffraction and energy-dispersive X-ray spectroscopy. The crystal structure comprises (100) sheets made up of [Ni(2)O(10)] dimers that are linked to two PO(4) tetra­hedra via common edges and vertices and of linear infinite [010] chains of corner-sharing [FeO(6)] octa­hedra and [PO(4)] tetra­hedra. The linkage of the sheets and chains into a framework is accomplished through common vertices of PO(4) tetra­hedra and [FeO(6)] octa­hedra. The framework is perforated by channels in which positionally disordered Ba(2+) cations are located. International Union of Crystallography 2023-01-17 /pmc/articles/PMC9912466/ /pubmed/36793405 http://dx.doi.org/10.1107/S2056989023000336 Text en © Ouaatta et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ouaatta, Said
Bouraima, Adam
Benhsina, Elhassan
Khmiyas, Jamal
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3)
title Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3)
title_full Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3)
title_fullStr Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3)
title_full_unstemmed Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3)
title_short Crystal structure of barium dinickel(II) iron(III) tris­[orthophosphate(V)], BaNi(2)Fe(PO(4))(3)
title_sort crystal structure of barium dinickel(ii) iron(iii) tris­[orthophosphate(v)], bani(2)fe(po(4))(3)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9912466/
https://www.ncbi.nlm.nih.gov/pubmed/36793405
http://dx.doi.org/10.1107/S2056989023000336
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