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Chemistry of CS(2) and CS(3) Bridged Decaborane Analogues: Regular Coordination Versus Cluster Expansion

In an effort to synthesize metallaheteroborane clusters of higher nuclearity, the reactivity of metallaheteroboranes, nido-[(Cp*M)(2)B(6)S(2)H(4)(CS(3))] (Cp* = C(5)Me(5)) (1: M = Co; 2: M = Rh) with various metal carbonyls have been investigated. Photolysis of nido-1 and nido-2 with group 6 metal c...

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Detalles Bibliográficos
Autores principales: Kar, Ketaki, Saha, Suvam, Parmar, Rahul Maganbhai, Roy, Arindam, Cordier, Marie, Roisnel, Thierry, Ghosh, Sundargopal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9919328/
https://www.ncbi.nlm.nih.gov/pubmed/36770666
http://dx.doi.org/10.3390/molecules28030998

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