Cargando…
Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal
TiO(2)-Kaolinite nanocomposite photocatalysts were synthesized using the sol-gel method, with titanium isopropoxide/HCl as reactants and Jordanian kaolinite clay as a support material. The samples’ TiO(2) content ranged from 10% to 70% (m/m). TiO(2)-Kaolinite composites were characterized using FTIR...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9919852/ https://www.ncbi.nlm.nih.gov/pubmed/36770657 http://dx.doi.org/10.3390/molecules28030989 |
_version_ | 1784886926631763968 |
---|---|
author | Alkhabbas, Manal Odeh, Fadwa Alzughoul, Khitam Afaneh, Razan Alahmad, Waed |
author_facet | Alkhabbas, Manal Odeh, Fadwa Alzughoul, Khitam Afaneh, Razan Alahmad, Waed |
author_sort | Alkhabbas, Manal |
collection | PubMed |
description | TiO(2)-Kaolinite nanocomposite photocatalysts were synthesized using the sol-gel method, with titanium isopropoxide/HCl as reactants and Jordanian kaolinite clay as a support material. The samples’ TiO(2) content ranged from 10% to 70% (m/m). TiO(2)-Kaolinite composites were characterized using FTIR, SEM, XRF, and XRD. According to XRD measurements of the nano-composite samples, the intensity of the anatase peaks increased as the TiO(2) percentage of the composition increased. As the percentage of TiO(2) increased, so did the peaks of Ti-O-Si in FTIR. The extent of photocatalytic degradation of Congo-red dye was used to evaluate the photocatalytic activity of the prepared nanocomposites. After four hours under the sun, the percentage of Congo-red degradation ranged from 27 to 99 percent depending on the TiO(2) content of the used nanocomposite. Meanwhile, the concentration drop in the dark did not exceed 10%. Photodegradation outperforms traditional treatment methods in terms of target degradation. Using naturally abundant materials such as clay in conjunction with metal oxides is widely regarded as an effective method of modifying the photoresponse properties of TiO(2) particles, thereby improving solar light harvesting for target degradation. |
format | Online Article Text |
id | pubmed-9919852 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-99198522023-02-12 Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal Alkhabbas, Manal Odeh, Fadwa Alzughoul, Khitam Afaneh, Razan Alahmad, Waed Molecules Article TiO(2)-Kaolinite nanocomposite photocatalysts were synthesized using the sol-gel method, with titanium isopropoxide/HCl as reactants and Jordanian kaolinite clay as a support material. The samples’ TiO(2) content ranged from 10% to 70% (m/m). TiO(2)-Kaolinite composites were characterized using FTIR, SEM, XRF, and XRD. According to XRD measurements of the nano-composite samples, the intensity of the anatase peaks increased as the TiO(2) percentage of the composition increased. As the percentage of TiO(2) increased, so did the peaks of Ti-O-Si in FTIR. The extent of photocatalytic degradation of Congo-red dye was used to evaluate the photocatalytic activity of the prepared nanocomposites. After four hours under the sun, the percentage of Congo-red degradation ranged from 27 to 99 percent depending on the TiO(2) content of the used nanocomposite. Meanwhile, the concentration drop in the dark did not exceed 10%. Photodegradation outperforms traditional treatment methods in terms of target degradation. Using naturally abundant materials such as clay in conjunction with metal oxides is widely regarded as an effective method of modifying the photoresponse properties of TiO(2) particles, thereby improving solar light harvesting for target degradation. MDPI 2023-01-18 /pmc/articles/PMC9919852/ /pubmed/36770657 http://dx.doi.org/10.3390/molecules28030989 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Alkhabbas, Manal Odeh, Fadwa Alzughoul, Khitam Afaneh, Razan Alahmad, Waed Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal |
title | Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal |
title_full | Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal |
title_fullStr | Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal |
title_full_unstemmed | Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal |
title_short | Jordanian Kaolinite with TiO(2) for Improving Solar Light Harvesting Used in Dye Removal |
title_sort | jordanian kaolinite with tio(2) for improving solar light harvesting used in dye removal |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9919852/ https://www.ncbi.nlm.nih.gov/pubmed/36770657 http://dx.doi.org/10.3390/molecules28030989 |
work_keys_str_mv | AT alkhabbasmanal jordaniankaolinitewithtio2forimprovingsolarlightharvestingusedindyeremoval AT odehfadwa jordaniankaolinitewithtio2forimprovingsolarlightharvestingusedindyeremoval AT alzughoulkhitam jordaniankaolinitewithtio2forimprovingsolarlightharvestingusedindyeremoval AT afanehrazan jordaniankaolinitewithtio2forimprovingsolarlightharvestingusedindyeremoval AT alahmadwaed jordaniankaolinitewithtio2forimprovingsolarlightharvestingusedindyeremoval |