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Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions

The potential use of magnetic nanopowder for phenol adsorption mobilised on natural grain carbon foam from an aqueous solution was studied. Phenolic compounds are priority pollutants with high toxicity even at low concentrations. A magnetic nanopowder was synthesised by dissolving an iron sponge in...

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Autores principales: Khumalo, Siphesihle Praise-God, Lokhat, David, Anwar, Chante Jasmine-Tre, Reddy, Huvin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920164/
https://www.ncbi.nlm.nih.gov/pubmed/36770937
http://dx.doi.org/10.3390/molecules28031272
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author Khumalo, Siphesihle Praise-God
Lokhat, David
Anwar, Chante Jasmine-Tre
Reddy, Huvin
author_facet Khumalo, Siphesihle Praise-God
Lokhat, David
Anwar, Chante Jasmine-Tre
Reddy, Huvin
author_sort Khumalo, Siphesihle Praise-God
collection PubMed
description The potential use of magnetic nanopowder for phenol adsorption mobilised on natural grain carbon foam from an aqueous solution was studied. Phenolic compounds are priority pollutants with high toxicity even at low concentrations. A magnetic nanopowder was synthesised by dissolving an iron sponge in nitric acid to produce iron nitrate, which was added to a natural grain mixture with flour as the main ingredient. The synthesised carbon foam was investigated for the effects of initial concentration, time, and TEM (transmission electron microscopy) characterisation. The phenol adsorption increased as the iron content of the carbon foam and the initial concentration increased. A kinetic study showed that the phenol adsorption data adequately covered all the carbon foam samples tested using an equation corresponding to a pseudo-first order chemical reaction. The Freundlich, Langmuir, and Temkin equations were tested for modelling the adsorption isotherms at equilibrium, and it was concluded that the Temkin model fit the experimental data adequately. Due to its exceptional physical and chemical properties, carbon magnetic nanopowder is regarded as an outstanding pollutant absorber in environmental investigations. R(2) values derived from the pseudo-first-order model exceed 0.99. R(2) > 0.94 indicates that the Freundlich isotherm provides the best fit to the equilibrium data.
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spelling pubmed-99201642023-02-12 Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions Khumalo, Siphesihle Praise-God Lokhat, David Anwar, Chante Jasmine-Tre Reddy, Huvin Molecules Article The potential use of magnetic nanopowder for phenol adsorption mobilised on natural grain carbon foam from an aqueous solution was studied. Phenolic compounds are priority pollutants with high toxicity even at low concentrations. A magnetic nanopowder was synthesised by dissolving an iron sponge in nitric acid to produce iron nitrate, which was added to a natural grain mixture with flour as the main ingredient. The synthesised carbon foam was investigated for the effects of initial concentration, time, and TEM (transmission electron microscopy) characterisation. The phenol adsorption increased as the iron content of the carbon foam and the initial concentration increased. A kinetic study showed that the phenol adsorption data adequately covered all the carbon foam samples tested using an equation corresponding to a pseudo-first order chemical reaction. The Freundlich, Langmuir, and Temkin equations were tested for modelling the adsorption isotherms at equilibrium, and it was concluded that the Temkin model fit the experimental data adequately. Due to its exceptional physical and chemical properties, carbon magnetic nanopowder is regarded as an outstanding pollutant absorber in environmental investigations. R(2) values derived from the pseudo-first-order model exceed 0.99. R(2) > 0.94 indicates that the Freundlich isotherm provides the best fit to the equilibrium data. MDPI 2023-01-28 /pmc/articles/PMC9920164/ /pubmed/36770937 http://dx.doi.org/10.3390/molecules28031272 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Khumalo, Siphesihle Praise-God
Lokhat, David
Anwar, Chante Jasmine-Tre
Reddy, Huvin
Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions
title Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions
title_full Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions
title_fullStr Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions
title_full_unstemmed Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions
title_short Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions
title_sort synthesis of iron on carbon foam for use in the removal of phenol from aqueous solutions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920164/
https://www.ncbi.nlm.nih.gov/pubmed/36770937
http://dx.doi.org/10.3390/molecules28031272
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