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Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions
The potential use of magnetic nanopowder for phenol adsorption mobilised on natural grain carbon foam from an aqueous solution was studied. Phenolic compounds are priority pollutants with high toxicity even at low concentrations. A magnetic nanopowder was synthesised by dissolving an iron sponge in...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920164/ https://www.ncbi.nlm.nih.gov/pubmed/36770937 http://dx.doi.org/10.3390/molecules28031272 |
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author | Khumalo, Siphesihle Praise-God Lokhat, David Anwar, Chante Jasmine-Tre Reddy, Huvin |
author_facet | Khumalo, Siphesihle Praise-God Lokhat, David Anwar, Chante Jasmine-Tre Reddy, Huvin |
author_sort | Khumalo, Siphesihle Praise-God |
collection | PubMed |
description | The potential use of magnetic nanopowder for phenol adsorption mobilised on natural grain carbon foam from an aqueous solution was studied. Phenolic compounds are priority pollutants with high toxicity even at low concentrations. A magnetic nanopowder was synthesised by dissolving an iron sponge in nitric acid to produce iron nitrate, which was added to a natural grain mixture with flour as the main ingredient. The synthesised carbon foam was investigated for the effects of initial concentration, time, and TEM (transmission electron microscopy) characterisation. The phenol adsorption increased as the iron content of the carbon foam and the initial concentration increased. A kinetic study showed that the phenol adsorption data adequately covered all the carbon foam samples tested using an equation corresponding to a pseudo-first order chemical reaction. The Freundlich, Langmuir, and Temkin equations were tested for modelling the adsorption isotherms at equilibrium, and it was concluded that the Temkin model fit the experimental data adequately. Due to its exceptional physical and chemical properties, carbon magnetic nanopowder is regarded as an outstanding pollutant absorber in environmental investigations. R(2) values derived from the pseudo-first-order model exceed 0.99. R(2) > 0.94 indicates that the Freundlich isotherm provides the best fit to the equilibrium data. |
format | Online Article Text |
id | pubmed-9920164 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-99201642023-02-12 Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions Khumalo, Siphesihle Praise-God Lokhat, David Anwar, Chante Jasmine-Tre Reddy, Huvin Molecules Article The potential use of magnetic nanopowder for phenol adsorption mobilised on natural grain carbon foam from an aqueous solution was studied. Phenolic compounds are priority pollutants with high toxicity even at low concentrations. A magnetic nanopowder was synthesised by dissolving an iron sponge in nitric acid to produce iron nitrate, which was added to a natural grain mixture with flour as the main ingredient. The synthesised carbon foam was investigated for the effects of initial concentration, time, and TEM (transmission electron microscopy) characterisation. The phenol adsorption increased as the iron content of the carbon foam and the initial concentration increased. A kinetic study showed that the phenol adsorption data adequately covered all the carbon foam samples tested using an equation corresponding to a pseudo-first order chemical reaction. The Freundlich, Langmuir, and Temkin equations were tested for modelling the adsorption isotherms at equilibrium, and it was concluded that the Temkin model fit the experimental data adequately. Due to its exceptional physical and chemical properties, carbon magnetic nanopowder is regarded as an outstanding pollutant absorber in environmental investigations. R(2) values derived from the pseudo-first-order model exceed 0.99. R(2) > 0.94 indicates that the Freundlich isotherm provides the best fit to the equilibrium data. MDPI 2023-01-28 /pmc/articles/PMC9920164/ /pubmed/36770937 http://dx.doi.org/10.3390/molecules28031272 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Khumalo, Siphesihle Praise-God Lokhat, David Anwar, Chante Jasmine-Tre Reddy, Huvin Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions |
title | Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions |
title_full | Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions |
title_fullStr | Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions |
title_full_unstemmed | Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions |
title_short | Synthesis of Iron on Carbon Foam for Use in the Removal of Phenol from Aqueous Solutions |
title_sort | synthesis of iron on carbon foam for use in the removal of phenol from aqueous solutions |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920164/ https://www.ncbi.nlm.nih.gov/pubmed/36770937 http://dx.doi.org/10.3390/molecules28031272 |
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