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σ-Aromatic MAl(6)S(6) (M = Ni, Pd, Pt) Stars Containing Planar Hexacoordinate Transition Metals

Hypercoordinate transition-metal species are mainly dominated by the 18-valence-electron (18ve) counting. Herein, we report ternary MAl(6)S(6) (M = Ni, Pd, Pt) clusters with the planar hexacoordinate metal (phM) centers, which feature 16ve counting instead of the classic 18ve rule. These global-mini...

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Detalles Bibliográficos
Autores principales:	Bai, Li-Xia, Guo, Jin-Chang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920543/ https://www.ncbi.nlm.nih.gov/pubmed/36770609 http://dx.doi.org/10.3390/molecules28030942

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