Cargando…

Ag–NHC Complexes in the π-Activation of Alkynes

Silver–NHC (NHC = N-heterocyclic carbene) complexes play a special role in the field of transition-metal complexes due to (1) their prominent biological activity, and (2) their critical role as transfer reagents for the synthesis of metal-NHC complexes by transmetalation. However, the application of...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yang, Shiyi, Zhou, Tongliang, Yu, Xiang, Szostak, Michal
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920927/ https://www.ncbi.nlm.nih.gov/pubmed/36770617 http://dx.doi.org/10.3390/molecules28030950

Ejemplares similares

Solvent-free hydroboration of alkynes catalyzed by an NHC–cobalt complex
por: Bołt, Małgorzata, et al.
Publicado: (2022)

Preparation of Butadienylpyridines by Iridium‐NHC‐Catalyzed Alkyne Hydroalkenylation and Quinolizine Rearrangement
por: Azpíroz, Ramón, et al.
Publicado: (2021)

[Pd(NHC)(μ-Cl)Cl](2): Versatile and Highly Reactive Complexes for Cross-Coupling Reactions that Avoid Formation of Inactive Pd(I) Off-Cycle Products
por: Zhou, Tongliang, et al.
Publicado: (2020)

Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes
por: Ferrer, Sofia, et al.
Publicado: (2017)

Addition of alkynes and osmium carbynes towards functionalized d(π)–p(π) conjugated systems
por: Chen, Shiyan, et al.
Publicado: (2020)

Efficient [(NHC)Au(NTf(2))]-catalyzed hydrohydrazidation of terminal and internal alkynes
por: Heidrich, Maximillian, et al.
Publicado: (2020)

Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes
por: Galiana‐Cameo, María, et al.
Publicado: (2022)

Biological Activities of Ruthenium NHC Complexes: An Update
por: Catalano, Alessia, et al.
Publicado: (2023)

[IPr(#)–PEPPSI]: A Well-Defined, Highly Hindered and Broadly Applicable Pd(II)–NHC (NHC = N-Heterocyclic Carbene) Precatalyst for Cross-Coupling Reactions
por: Rahman, Md. Mahbubur, et al.
Publicado: (2023)

NHC–BIAN–Cu(I)-Catalyzed Friedländer-Type Annulation of 2-Amino-3-(per)fluoroacetylpyridines with Alkynes on Water
por: Dolna, Magdalena, et al.
Publicado: (2022)

NHC Pd(II) and Ag(I) Complexes: Synthesis, Structure, and Catalytic Activity in Three Types of C–C Coupling Reactions
por: Liu, Qing-Xiang, et al.
Publicado: (2018)

Pyridine Wingtip in [Pd(Py-tzNHC)(2)](2+) Complex Is a Proton Shuttle in the Catalytic Hydroamination of Alkynes
por: Virant, Miha, et al.
Publicado: (2020)

Case Study of N‐( i )Pr versus N‐Mes Substituted NHC Ligands in Nickel Chemistry: The Coordination and Cyclotrimerization of Alkynes at [Ni(NHC)(2)]
por: Tendera, Lukas, et al.
Publicado: (2021)

Structure–Activity Relationships in NHC–Silver Complexes as Antimicrobial Agents
por: Ronga, Luisa, et al.
Publicado: (2023)

Rh(I) Complexes with Hemilabile Thioether-Functionalized NHC Ligands as Catalysts for [2 + 2 + 2] Cycloaddition of 1,5-Bisallenes and Alkynes
por: Vila, Jordi, et al.
Publicado: (2023)

Synthesis of an [(NHC)(2)Pd(SiMe(3))(2)] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes**
por: Ansell, Melvyn B, et al.
Publicado: (2015)

NHC stabilized copper nanoparticles via reduction of a copper NHC complex
por: Richstein, Robert, et al.
Publicado: (2023)

Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion
por: Kumar, Puneet, et al.
Publicado: (2014)

Transamidation of Amides and Amidation of Esters by Selective N–C(O)/O–C(O) Cleavage Mediated by Air- and Moisture-Stable Half-Sandwich Nickel(II)–NHC Complexes
por: Buchspies, Jonathan, et al.
Publicado: (2021)

The key role of R–NHC coupling (R = C, H, heteroatom) and M–NHC bond cleavage in the evolution of M/NHC complexes and formation of catalytically active species
por: Chernyshev, Victor M., et al.
Publicado: (2020)

Palladium-catalyzed decarbonylative Suzuki–Miyaura cross-coupling of amides by carbon–nitrogen bond activation
por: Zhou, Tongliang, et al.
Publicado: (2019)

Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights
por: González-Lainez, Miguel, et al.
Publicado: (2022)

A Fluoroponytailed NHC–Silver Complex Formed from Vinylimidazolium/AgNO(3) under Aqueous–Ammoniacal Conditions †
por: Partl, Gabriel, et al.
Publicado: (2022)

π‐Extended Polyaromatic Hydrocarbons by Sustainable Alkyne Annulations through Double C−H/N−H Activation
por: Gońka, Elżbieta, et al.
Publicado: (2019)

π–π Stacking Interaction of Metal Phenoxyl Radical Complexes
por: Oshita, Hiromi, et al.
Publicado: (2022)

Recent Developments in the Medicinal Applications of Silver-NHC Complexes and Imidazolium Salts
por: Johnson, Nicholas A., et al.
Publicado: (2017)

Possible Synthetic Approaches for Heterobimetallic Complexes by Using nNHC/tzNHC Heteroditopic Carbene Ligands
por: Longhi, Andrea, et al.
Publicado: (2019)

On the Different Mode of Action of Au(I)/Ag(I)-NHC Bis-Anthracenyl Complexes Towards Selected Target Biomolecules
por: Binacchi, Francesca, et al.
Publicado: (2020)

Activation of Molecular Oxygen by a Cobalt(II) Tetra‐NHC Complex
por: Schlagintweit, Jonas F., et al.
Publicado: (2020)

NHC-Metallosurfactants as Active Polymerization Catalysts
por: Donner, Adrian, et al.
Publicado: (2019)

Unexpected reactions of NHC*—Cu(I) and —Ag(I) bromides with potassium thio- or selenocyanate
por: Tacke, Matthias, et al.
Publicado: (2019)

Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis
por: Chernyshev, Victor M., et al.
Publicado: (2018)

Biological Activity of NHC-Gold-Alkynyl Complexes Derived from 3-Hydroxyflavones
por: Mármol, Inés, et al.
Publicado: (2022)

N-Alkylation and N-Methylation of Amines with Alcohols Catalyzed by Nitrile-Substituted NHC–Ir(III) and NHC–Ru(II) Complexes
por: Çakır, Sinem, et al.
Publicado: (2023)

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
por: Santoro, Orlando, et al.
Publicado: (2013)

An NHC‐Mediated Metal‐Free Approach towards an NHC‐Coordinated Endocyclic Disilene
por: Lainer, Thomas, et al.
Publicado: (2022)

New Insights into the Behavior of NHC-Gold Complexes in Cancer Cells
por: Augello, Giuseppa, et al.
Publicado: (2023)

Reactivity and Structure of a Bis-phenolate Niobium NHC Complex
por: Neururer, Florian R., et al.
Publicado: (2022)

Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
por: Shoji, Yoshiaki, et al.
Publicado: (2016)

Synthesis of Aminoallenes via Selenium‐π‐Acid‐Catalyzed Cross‐Coupling of N‐Fluorinated Sulfonimides with Simple Alkynes
por: Rode, Katharina, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_taup087obsans24retqovlh95i