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Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation

Photocatalytic oxidation is considered one of the most effective ways to remove formaldehyde from indoor air. However, the use of powder photocatalysts is limited by their low adsorption capacity and strong aggregation tendency. Hence, there is a need for a composite material with good cycling stabi...

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Autores principales: Lv, Zhiqiang, Ma, Yi, Jia, Shanshan, Qing, Yan, Li, Lei, Chen, Yangyang, Wu, Yiqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921009/
https://www.ncbi.nlm.nih.gov/pubmed/36770650
http://dx.doi.org/10.3390/molecules28030972
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author Lv, Zhiqiang
Ma, Yi
Jia, Shanshan
Qing, Yan
Li, Lei
Chen, Yangyang
Wu, Yiqiang
author_facet Lv, Zhiqiang
Ma, Yi
Jia, Shanshan
Qing, Yan
Li, Lei
Chen, Yangyang
Wu, Yiqiang
author_sort Lv, Zhiqiang
collection PubMed
description Photocatalytic oxidation is considered one of the most effective ways to remove formaldehyde from indoor air. However, the use of powder photocatalysts is limited by their low adsorption capacity and strong aggregation tendency. Hence, there is a need for a composite material with good cycling stability and high degradation efficiency. In the present study, a unique wood-based composite is produced by arranging Cu–TiO(2) nanoparticles on porous structured wood. The porous structure of wood can adsorb formaldehyde, and the abundant functional groups on the surface can act as a reaction platform for anchoring the Cu–TiO(2) nanoparticles. Cu doping facilitates electron interaction between TiO(2) and Cu, promotes the transfer of charge carriers, lowers the electron–hole recombination rate, and improves the photocatalytic degradation efficiency of formaldehyde. The photocatalytic efficiency of the wood-based composites was highest (85.59%) when the n(Cu)/n(Ti) ratio was 7%. After nine cycles, the wood composites still had a high degradation rate, indicating good recyclability. Overall, this wood composite is an eco-friendly and promising material for indoor air filtration.
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spelling pubmed-99210092023-02-12 Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation Lv, Zhiqiang Ma, Yi Jia, Shanshan Qing, Yan Li, Lei Chen, Yangyang Wu, Yiqiang Molecules Article Photocatalytic oxidation is considered one of the most effective ways to remove formaldehyde from indoor air. However, the use of powder photocatalysts is limited by their low adsorption capacity and strong aggregation tendency. Hence, there is a need for a composite material with good cycling stability and high degradation efficiency. In the present study, a unique wood-based composite is produced by arranging Cu–TiO(2) nanoparticles on porous structured wood. The porous structure of wood can adsorb formaldehyde, and the abundant functional groups on the surface can act as a reaction platform for anchoring the Cu–TiO(2) nanoparticles. Cu doping facilitates electron interaction between TiO(2) and Cu, promotes the transfer of charge carriers, lowers the electron–hole recombination rate, and improves the photocatalytic degradation efficiency of formaldehyde. The photocatalytic efficiency of the wood-based composites was highest (85.59%) when the n(Cu)/n(Ti) ratio was 7%. After nine cycles, the wood composites still had a high degradation rate, indicating good recyclability. Overall, this wood composite is an eco-friendly and promising material for indoor air filtration. MDPI 2023-01-18 /pmc/articles/PMC9921009/ /pubmed/36770650 http://dx.doi.org/10.3390/molecules28030972 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Lv, Zhiqiang
Ma, Yi
Jia, Shanshan
Qing, Yan
Li, Lei
Chen, Yangyang
Wu, Yiqiang
Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation
title Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation
title_full Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation
title_fullStr Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation
title_full_unstemmed Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation
title_short Synthesis of Cu-Doped TiO(2) on Wood Substrate with Highly Efficient Photocatalytic Performance and Outstanding Recyclability for Formaldehyde Degradation
title_sort synthesis of cu-doped tio(2) on wood substrate with highly efficient photocatalytic performance and outstanding recyclability for formaldehyde degradation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921009/
https://www.ncbi.nlm.nih.gov/pubmed/36770650
http://dx.doi.org/10.3390/molecules28030972
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