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Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier

The role of solvents is crucial in catalyst preparation. With regard to catalysts prepared with activated carbon (AC) as the carrier, when water is used as a solvent it is difficult for the solution to infiltrate the AC. Because AC comprises a large number of C atoms and is a nonpolar material, it i...

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Autores principales: Xu, Zhuang, Li, Mengli, Shen, Guowang, Chen, Yuhao, Lu, Dashun, Ren, Peng, Jiang, Hao, Wang, Xugen, Dai, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921317/
https://www.ncbi.nlm.nih.gov/pubmed/36770353
http://dx.doi.org/10.3390/nano13030393
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author Xu, Zhuang
Li, Mengli
Shen, Guowang
Chen, Yuhao
Lu, Dashun
Ren, Peng
Jiang, Hao
Wang, Xugen
Dai, Bin
author_facet Xu, Zhuang
Li, Mengli
Shen, Guowang
Chen, Yuhao
Lu, Dashun
Ren, Peng
Jiang, Hao
Wang, Xugen
Dai, Bin
author_sort Xu, Zhuang
collection PubMed
description The role of solvents is crucial in catalyst preparation. With regard to catalysts prepared with activated carbon (AC) as the carrier, when water is used as a solvent it is difficult for the solution to infiltrate the AC. Because AC comprises a large number of C atoms and is a nonpolar material, it is more effective for the adsorption of nonpolar substances. Since the water and active ingredients are polar, they cannot easily infiltrate AC. In this study, the dispersion of the active component was significantly improved by optimizing the solvent, and the particle size of the active component was reduced from 33.08 nm to 15.30 nm. The specific surface area of the catalyst is significantly increased, by 10%, reaching 991.49 m(2)/g. Under the same reaction conditions, the conversion of acetic acid by the catalyst prepared with the mixed solvent was maintained at approximately 65%, which was 22% higher than that obtained using the catalyst prepared with water as the solvent.
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spelling pubmed-99213172023-02-12 Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier Xu, Zhuang Li, Mengli Shen, Guowang Chen, Yuhao Lu, Dashun Ren, Peng Jiang, Hao Wang, Xugen Dai, Bin Nanomaterials (Basel) Article The role of solvents is crucial in catalyst preparation. With regard to catalysts prepared with activated carbon (AC) as the carrier, when water is used as a solvent it is difficult for the solution to infiltrate the AC. Because AC comprises a large number of C atoms and is a nonpolar material, it is more effective for the adsorption of nonpolar substances. Since the water and active ingredients are polar, they cannot easily infiltrate AC. In this study, the dispersion of the active component was significantly improved by optimizing the solvent, and the particle size of the active component was reduced from 33.08 nm to 15.30 nm. The specific surface area of the catalyst is significantly increased, by 10%, reaching 991.49 m(2)/g. Under the same reaction conditions, the conversion of acetic acid by the catalyst prepared with the mixed solvent was maintained at approximately 65%, which was 22% higher than that obtained using the catalyst prepared with water as the solvent. MDPI 2023-01-18 /pmc/articles/PMC9921317/ /pubmed/36770353 http://dx.doi.org/10.3390/nano13030393 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Xu, Zhuang
Li, Mengli
Shen, Guowang
Chen, Yuhao
Lu, Dashun
Ren, Peng
Jiang, Hao
Wang, Xugen
Dai, Bin
Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier
title Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier
title_full Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier
title_fullStr Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier
title_full_unstemmed Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier
title_short Solvent Effects in the Preparation of Catalysts Using Activated Carbon as a Carrier
title_sort solvent effects in the preparation of catalysts using activated carbon as a carrier
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921317/
https://www.ncbi.nlm.nih.gov/pubmed/36770353
http://dx.doi.org/10.3390/nano13030393
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