Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs

For the first time a pyrrolidinofullerene salt containing a spiropyran group and an ammonium group, capable of reversibly reacting to UV radiation, has been synthesized. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, spectral and ki...

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Autores principales: Khuzin, Artur A., Galimov, Dim I., Khuzina, Liliya L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921579/
https://www.ncbi.nlm.nih.gov/pubmed/36770772
http://dx.doi.org/10.3390/molecules28031107
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author Khuzin, Artur A.
Galimov, Dim I.
Khuzina, Liliya L.
author_facet Khuzin, Artur A.
Galimov, Dim I.
Khuzina, Liliya L.
author_sort Khuzin, Artur A.
collection PubMed
description For the first time a pyrrolidinofullerene salt containing a spiropyran group and an ammonium group, capable of reversibly reacting to UV radiation, has been synthesized. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, spectral and kinetic characteristics were measured. The hybrid molecule was found to exhibit intrinsic fluorescence even in the spirocyclic form. The C(60) derivative showed a higher stability and better spectral and luminescent properties than the precursor.
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spelling pubmed-99215792023-02-12 Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs Khuzin, Artur A. Galimov, Dim I. Khuzina, Liliya L. Molecules Communication For the first time a pyrrolidinofullerene salt containing a spiropyran group and an ammonium group, capable of reversibly reacting to UV radiation, has been synthesized. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, spectral and kinetic characteristics were measured. The hybrid molecule was found to exhibit intrinsic fluorescence even in the spirocyclic form. The C(60) derivative showed a higher stability and better spectral and luminescent properties than the precursor. MDPI 2023-01-22 /pmc/articles/PMC9921579/ /pubmed/36770772 http://dx.doi.org/10.3390/molecules28031107 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Khuzin, Artur A.
Galimov, Dim I.
Khuzina, Liliya L.
Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs
title Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs
title_full Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs
title_fullStr Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs
title_full_unstemmed Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs
title_short Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C(60) Fullerene and Spiropyran—A Promising Approach to the Creation of Anticancer Drugs
title_sort photochromic and luminescent properties of a salt of a hybrid molecule based on c(60) fullerene and spiropyran—a promising approach to the creation of anticancer drugs
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921579/
https://www.ncbi.nlm.nih.gov/pubmed/36770772
http://dx.doi.org/10.3390/molecules28031107
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