Cargando…

Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests

Wood coatings prolong the service life of wood-based products, but they are usually of synthetic origin. The aim of the present article is to reduce the fossil-based compounds in a commercial waterborne acrylic coating by CNC addition and to test its performance. The coatings were applied on Europea...

Descripción completa

Detalles Bibliográficos
Autores principales: Tamantini, Swati, Bergamasco, Sara, Zikeli, Florian, Humar, Miha, Cavalera, Massimo, Romagnoli, Manuela
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921673/
https://www.ncbi.nlm.nih.gov/pubmed/36770403
http://dx.doi.org/10.3390/nano13030442
_version_ 1784887368045559808
author Tamantini, Swati
Bergamasco, Sara
Zikeli, Florian
Humar, Miha
Cavalera, Massimo
Romagnoli, Manuela
author_facet Tamantini, Swati
Bergamasco, Sara
Zikeli, Florian
Humar, Miha
Cavalera, Massimo
Romagnoli, Manuela
author_sort Tamantini, Swati
collection PubMed
description Wood coatings prolong the service life of wood-based products, but they are usually of synthetic origin. The aim of the present article is to reduce the fossil-based compounds in a commercial waterborne acrylic coating by CNC addition and to test its performance. The coatings were applied on European beech and Norway spruce wood in order to test durability against Gloeophyllum trabeum (brown wood rot) and Trametes versicolor (white wood rot). Artificial weathering and blue stain, contact angle, physical tests (adhesion, impact and scratch test), chemical (FTIR) and morpho-anatomical analysis (SEM) were carried out. CNC addition increased viscosity, limiting the spreading of the coating into wood pores as visible after SEM observation, which reduced coating adhesion on the substrate. CNC improved fungal resistance as seen by a reduced mass loss and FTIR spectroscopy thanks to crosslinks formation, which reduced water sorption as well. Color change was not significant, and, on the other hand, glossiness was reduced but resulted as more homogeneous than control. CNC addition gave good results also in blue stain protection. CNC improved scratch resistance, but no visible change to impact was registered. CNC has promising results in coatings depending on wood and fungal species and presence of further commercial additives (biocides).
format Online
Article
Text
id pubmed-9921673
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-99216732023-02-12 Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests Tamantini, Swati Bergamasco, Sara Zikeli, Florian Humar, Miha Cavalera, Massimo Romagnoli, Manuela Nanomaterials (Basel) Article Wood coatings prolong the service life of wood-based products, but they are usually of synthetic origin. The aim of the present article is to reduce the fossil-based compounds in a commercial waterborne acrylic coating by CNC addition and to test its performance. The coatings were applied on European beech and Norway spruce wood in order to test durability against Gloeophyllum trabeum (brown wood rot) and Trametes versicolor (white wood rot). Artificial weathering and blue stain, contact angle, physical tests (adhesion, impact and scratch test), chemical (FTIR) and morpho-anatomical analysis (SEM) were carried out. CNC addition increased viscosity, limiting the spreading of the coating into wood pores as visible after SEM observation, which reduced coating adhesion on the substrate. CNC improved fungal resistance as seen by a reduced mass loss and FTIR spectroscopy thanks to crosslinks formation, which reduced water sorption as well. Color change was not significant, and, on the other hand, glossiness was reduced but resulted as more homogeneous than control. CNC addition gave good results also in blue stain protection. CNC improved scratch resistance, but no visible change to impact was registered. CNC has promising results in coatings depending on wood and fungal species and presence of further commercial additives (biocides). MDPI 2023-01-21 /pmc/articles/PMC9921673/ /pubmed/36770403 http://dx.doi.org/10.3390/nano13030442 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tamantini, Swati
Bergamasco, Sara
Zikeli, Florian
Humar, Miha
Cavalera, Massimo
Romagnoli, Manuela
Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests
title Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests
title_full Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests
title_fullStr Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests
title_full_unstemmed Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests
title_short Cellulose Nano Crystals (CNC) as Additive for a Bio-Based Waterborne Acrylic Wood Coating: Decay, Artificial Weathering, Physical and Chemical Tests
title_sort cellulose nano crystals (cnc) as additive for a bio-based waterborne acrylic wood coating: decay, artificial weathering, physical and chemical tests
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921673/
https://www.ncbi.nlm.nih.gov/pubmed/36770403
http://dx.doi.org/10.3390/nano13030442
work_keys_str_mv AT tamantiniswati cellulosenanocrystalscncasadditiveforabiobasedwaterborneacrylicwoodcoatingdecayartificialweatheringphysicalandchemicaltests
AT bergamascosara cellulosenanocrystalscncasadditiveforabiobasedwaterborneacrylicwoodcoatingdecayartificialweatheringphysicalandchemicaltests
AT zikeliflorian cellulosenanocrystalscncasadditiveforabiobasedwaterborneacrylicwoodcoatingdecayartificialweatheringphysicalandchemicaltests
AT humarmiha cellulosenanocrystalscncasadditiveforabiobasedwaterborneacrylicwoodcoatingdecayartificialweatheringphysicalandchemicaltests
AT cavaleramassimo cellulosenanocrystalscncasadditiveforabiobasedwaterborneacrylicwoodcoatingdecayartificialweatheringphysicalandchemicaltests
AT romagnolimanuela cellulosenanocrystalscncasadditiveforabiobasedwaterborneacrylicwoodcoatingdecayartificialweatheringphysicalandchemicaltests