A Chiral Amine Transfer Approach to the Photocatalytic Asymmetric Synthesis of α-Trialkyl-α-tertiary Amines

[Image: see text] A long-standing challenge within radical chemistry is that of controlling the absolute stereochemistry of the products. Here, we report the stereocontrolled addition of α-amino radicals reductively generated from imines via visible-light-mediated photoredox-catalysis to alkenes, gi...

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Detalles Bibliográficos
Autores principales: Harris, Georgia R., Trowbridge, Aaron D., Gaunt, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9926512/
https://www.ncbi.nlm.nih.gov/pubmed/36724345
http://dx.doi.org/10.1021/acs.orglett.2c04308

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9926512/
https://www.ncbi.nlm.nih.gov/pubmed/36724345
http://dx.doi.org/10.1021/acs.orglett.2c04308

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