Chemical Evaluation and Performance Characterization of Pentaerythritol Tetranitrate (PETN) under Melt Conditions

[Image: see text] Pentaerythritol tetranitrate (PETN) is a nitrate ester explosive commonly used in commercial detonators. Although its degradation properties have been studied extensively, very little information has been collected on its thermal stability in the molten state due to the fact that its melting point is only ∼20 °C below its onset of decomposition. Furthermore, studies that have been performed on PETN thermal degradation often do not fully characterize or quantify the decomposition products. In this study, we heat PETN to melt temperatures and identify thermal decomposition products, morphology changes, and mass loss by ultrahigh-pressure liquid chromatography coupled to quadrupole time of flight mass spectrometry, scanning electron microscopy, nuclear magnetic resonance spectroscopy, and differential scanning calorimetry. For the first time, we quantify several decomposition products using independently prepared standards and establish the resulting melting point depression after the first melt. We also estimate the amount of decomposition relative to sublimation that we measure through gas evolution and evaluate the performance behavior of the molten material in commercial detonator configurations.