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Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution

The influence of double-headed gemini was examined in the present study by studying the amino acid methionine mixed with ninhydrin in CH(3)COOH-CH(3)COONa buffer solvent. The absorbance was monitored at fixed time intervals with UV-vis spectroscopy. An impact typical of surfactants was observed on t...

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Autores principales: Alghamdi, Yousef G., Rub, Malik Abdul, Kumar, Dileep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9929513/
https://www.ncbi.nlm.nih.gov/pubmed/36816844
http://dx.doi.org/10.1098/rsos.221249
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author Alghamdi, Yousef G.
Rub, Malik Abdul
Kumar, Dileep
author_facet Alghamdi, Yousef G.
Rub, Malik Abdul
Kumar, Dileep
author_sort Alghamdi, Yousef G.
collection PubMed
description The influence of double-headed gemini was examined in the present study by studying the amino acid methionine mixed with ninhydrin in CH(3)COOH-CH(3)COONa buffer solvent. The absorbance was monitored at fixed time intervals with UV-vis spectroscopy. An impact typical of surfactants was observed on the ninhydrin–methionine reaction and explained by a pseudo-phase model of micelles. The effect of different temperatures (343 to 363 K) was also determined. Based on data showing the impact of temperature on k(ψ), several relevant thermodynamic quantities, ΔH(#), ΔS(#), and E(a), were calculated using linear least-squares regression. In addition, the influence of the other reaction ingredients on the reaction, that is, pH and the concentration of ninhydrin and methionine, was studied. The CMC (critical micelle concentration) of pure geminis and the surfactant system with methionine and ninhydrin was evaluated at two temperatures, i.e. at 303 K and 353 K by conductivity measurements. The CMC values of pure gemini surfactants evaluated in the existing case at 303 K are concordant with the results stated before. Moreover, other parameters, including rates and binding constants, were calculated.
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spelling pubmed-99295132023-02-16 Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution Alghamdi, Yousef G. Rub, Malik Abdul Kumar, Dileep R Soc Open Sci Chemistry The influence of double-headed gemini was examined in the present study by studying the amino acid methionine mixed with ninhydrin in CH(3)COOH-CH(3)COONa buffer solvent. The absorbance was monitored at fixed time intervals with UV-vis spectroscopy. An impact typical of surfactants was observed on the ninhydrin–methionine reaction and explained by a pseudo-phase model of micelles. The effect of different temperatures (343 to 363 K) was also determined. Based on data showing the impact of temperature on k(ψ), several relevant thermodynamic quantities, ΔH(#), ΔS(#), and E(a), were calculated using linear least-squares regression. In addition, the influence of the other reaction ingredients on the reaction, that is, pH and the concentration of ninhydrin and methionine, was studied. The CMC (critical micelle concentration) of pure geminis and the surfactant system with methionine and ninhydrin was evaluated at two temperatures, i.e. at 303 K and 353 K by conductivity measurements. The CMC values of pure gemini surfactants evaluated in the existing case at 303 K are concordant with the results stated before. Moreover, other parameters, including rates and binding constants, were calculated. The Royal Society 2023-02-15 /pmc/articles/PMC9929513/ /pubmed/36816844 http://dx.doi.org/10.1098/rsos.221249 Text en © 2023 The Authors. https://creativecommons.org/licenses/by/4.0/Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, provided the original author and source are credited.
spellingShingle Chemistry
Alghamdi, Yousef G.
Rub, Malik Abdul
Kumar, Dileep
Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution
title Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution
title_full Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution
title_fullStr Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution
title_full_unstemmed Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution
title_short Influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution
title_sort influence of twin-headed gemini micellar system on the study of methionine amino acid with ninhydrin in buffer solution
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9929513/
https://www.ncbi.nlm.nih.gov/pubmed/36816844
http://dx.doi.org/10.1098/rsos.221249
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