Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR

[Image: see text] Two propeller-shaped chiral Co(III)(3)Y(III) complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization m...

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Autores principales: Audsley, Gabrielle, Carpenter, Harry, Essien, Nsikak B., Lai-Morrice, James, Al-Hilaly, Youssra, Serpell, Louise C., Akien, Geoffrey R., Tizzard, Graham J., Coles, Simon J., Ulldemolins, Cristina Pubill, Kostakis, George E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930122/
https://www.ncbi.nlm.nih.gov/pubmed/36716401
http://dx.doi.org/10.1021/acs.inorgchem.2c03737
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author Audsley, Gabrielle
Carpenter, Harry
Essien, Nsikak B.
Lai-Morrice, James
Al-Hilaly, Youssra
Serpell, Louise C.
Akien, Geoffrey R.
Tizzard, Graham J.
Coles, Simon J.
Ulldemolins, Cristina Pubill
Kostakis, George E.
author_facet Audsley, Gabrielle
Carpenter, Harry
Essien, Nsikak B.
Lai-Morrice, James
Al-Hilaly, Youssra
Serpell, Louise C.
Akien, Geoffrey R.
Tizzard, Graham J.
Coles, Simon J.
Ulldemolins, Cristina Pubill
Kostakis, George E.
author_sort Audsley, Gabrielle
collection PubMed
description [Image: see text] Two propeller-shaped chiral Co(III)(3)Y(III) complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR ((1)H, (13)C, and (19)F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a (19)F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.
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spelling pubmed-99301222023-02-16 Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR Audsley, Gabrielle Carpenter, Harry Essien, Nsikak B. Lai-Morrice, James Al-Hilaly, Youssra Serpell, Louise C. Akien, Geoffrey R. Tizzard, Graham J. Coles, Simon J. Ulldemolins, Cristina Pubill Kostakis, George E. Inorg Chem [Image: see text] Two propeller-shaped chiral Co(III)(3)Y(III) complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR ((1)H, (13)C, and (19)F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a (19)F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented. American Chemical Society 2023-01-30 /pmc/articles/PMC9930122/ /pubmed/36716401 http://dx.doi.org/10.1021/acs.inorgchem.2c03737 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Audsley, Gabrielle
Carpenter, Harry
Essien, Nsikak B.
Lai-Morrice, James
Al-Hilaly, Youssra
Serpell, Louise C.
Akien, Geoffrey R.
Tizzard, Graham J.
Coles, Simon J.
Ulldemolins, Cristina Pubill
Kostakis, George E.
Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR
title Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR
title_full Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR
title_fullStr Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR
title_full_unstemmed Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR
title_short Chiral Co(3)Y Propeller-Shaped Chemosensory Platforms Based on (19)F-NMR
title_sort chiral co(3)y propeller-shaped chemosensory platforms based on (19)f-nmr
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930122/
https://www.ncbi.nlm.nih.gov/pubmed/36716401
http://dx.doi.org/10.1021/acs.inorgchem.2c03737
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