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Sulfur-Ligated [2Fe-2C] Clusters as Synthetic Model Systems for Nitrogenase
[Image: see text] Metal clusters featuring carbon and sulfur donors have coordination environments comparable to the active site of nitrogenase enzymes. Here, we report a series of di-iron clusters supported by the dianionic yldiide ligands, in which the Fe sites are bridged by two μ(2)-C atoms and...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930126/ https://www.ncbi.nlm.nih.gov/pubmed/36715662 http://dx.doi.org/10.1021/acs.inorgchem.2c03693 |