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Sulfur-Ligated [2Fe-2C] Clusters as Synthetic Model Systems for Nitrogenase

[Image: see text] Metal clusters featuring carbon and sulfur donors have coordination environments comparable to the active site of nitrogenase enzymes. Here, we report a series of di-iron clusters supported by the dianionic yldiide ligands, in which the Fe sites are bridged by two μ(2)-C atoms and...

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Detalles Bibliográficos
Autores principales:	Yogendra, Sivathmeehan, Wilson, Daniel W. N., Hahn, Anselm W., Weyhermüller, Thomas, Van Stappen, Casey, Holland, Patrick, DeBeer, Serena
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930126/ https://www.ncbi.nlm.nih.gov/pubmed/36715662 http://dx.doi.org/10.1021/acs.inorgchem.2c03693

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