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Asymmetric synthesis of complex tricyclo[3.2.2.0]nonenes from racemic norcaradienes: kinetic resolution via Diels–Alder reaction

Herein, the enantioselective synthesis of complex tricyclo[3.2.2.0]nonenes through the Diels–Alder reaction is reported. Utilizing racemic norcaradienes prepared from the visible-light-mediated dearomative cyclopropanation of m-xylene as dienes and enone derivatives as dienophiles, the overall proce...

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Detalles Bibliográficos
Autores principales: Wang, Siyuan, Zhou, Yuqiao, Xiao, Wanlong, Li, Zegong, Liu, Xiaohua, Feng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930936/
https://www.ncbi.nlm.nih.gov/pubmed/36819855
http://dx.doi.org/10.1039/d2sc06490a