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Asymmetric synthesis of complex tricyclo[3.2.2.0]nonenes from racemic norcaradienes: kinetic resolution via Diels–Alder reaction
Herein, the enantioselective synthesis of complex tricyclo[3.2.2.0]nonenes through the Diels–Alder reaction is reported. Utilizing racemic norcaradienes prepared from the visible-light-mediated dearomative cyclopropanation of m-xylene as dienes and enone derivatives as dienophiles, the overall proce...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930936/ https://www.ncbi.nlm.nih.gov/pubmed/36819855 http://dx.doi.org/10.1039/d2sc06490a |