Cargando…

Asymmetric synthesis of complex tricyclo[3.2.2.0]nonenes from racemic norcaradienes: kinetic resolution via Diels–Alder reaction

Herein, the enantioselective synthesis of complex tricyclo[3.2.2.0]nonenes through the Diels–Alder reaction is reported. Utilizing racemic norcaradienes prepared from the visible-light-mediated dearomative cyclopropanation of m-xylene as dienes and enone derivatives as dienophiles, the overall proce...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Siyuan, Zhou, Yuqiao, Xiao, Wanlong, Li, Zegong, Liu, Xiaohua, Feng, Xiaoming
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930936/ https://www.ncbi.nlm.nih.gov/pubmed/36819855 http://dx.doi.org/10.1039/d2sc06490a

Ejemplares similares

Enantioselective construction of cis-hydroindole scaffolds via an asymmetric inverse-electron-demand Diels–Alder reaction: application to the formal total synthesis of (+)-minovincine
por: Zhang, Fangqing, et al.
Publicado: (2022)

Asymmetric pyrone Diels–Alder reactions enabled by dienamine catalysis
por: Cole, Charles J. F., et al.
Publicado: (2019)

Catalytic asymmetric oxa-Diels–Alder reaction of acroleins with simple alkenes
por: Zeng, Lei, et al.
Publicado: (2023)

Catalytic asymmetric oxo-Diels–Alder reactions with chiral atropisomeric biphenyl diols
por: Yeung, Chi-Tung, et al.
Publicado: (2019)

The hexadehydro-Diels–Alder reaction
por: Hoye, Thomas R., et al.
Publicado: (2012)

The pentadehydro-Diels–Alder reaction
por: Wang, Teng, et al.
Publicado: (2016)

An on‐surface Diels–Alder reaction
por: Castro‐Esteban, Jesús, et al.
Publicado: (2021)

Simple organocatalyst component system for asymmetric hetero Diels–Alder reaction of isatins with enones
por: Parasuraman, Perumalsamy, et al.
Publicado: (2020)

Origin of asynchronicity in Diels–Alder reactions
por: Vermeeren, Pascal, et al.
Publicado: (2021)

Catalytic Asymmetric Diels–Alder Reaction of 2′-Hydroxychalcone as a Dienophile with a VANOL-Borate Ester Complex
por: Li, Xia, et al.
Publicado: (2023)

Total synthesis of (+)-gelsemine via an organocatalytic Diels–Alder approach
por: Chen, Xiaoming, et al.
Publicado: (2015)

Asymmetric Synthesis of [2.2.2]-Bicyclic Lactones via All-Carbon Inverse-Electron-Demand Diels–Alder Reaction
por: Saktura, Maciej, et al.
Publicado: (2020)

Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
por: Pégot, Bruce, et al.
Publicado: (2006)

Asymmetric Brønsted acid-catalyzed aza-Diels–Alder reaction of cyclic C-acylimines with cyclopentadiene
por: Rueping, Magnus, et al.
Publicado: (2012)

Diels–Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels–Alder reaction
por: Cantín, Ángel, et al.
Publicado: (2016)

Oxidative Asymmetric Formal Aza-Diels–Alder Reactions of Tetrahydro-β-carboline with Enones in the Synthesis of Indoloquinolizidine-2-ones
por: Wu, Xiang, et al.
Publicado: (2018)

Dual Activation of Aromatic Diels–Alder Reactions
por: Narsaria, Ayush K., et al.
Publicado: (2019)

Diels–Alder Reactions During the Biosynthesis of Sorbicillinoids
por: Kahlert, Lukas, et al.
Publicado: (2020)

Diels–Alder Cycloaddition Reactions in Sustainable Media
por: Soares, Maria I. L., et al.
Publicado: (2022)

The simplest Diels–Alder reactions are not endo-selective
por: Lording, William J., et al.
Publicado: (2020)

How Ionization Catalyzes Diels‐Alder Reactions
por: Vermeeren, Pascal, et al.
Publicado: (2022)

Enantioselective oxa‐Diels–Alder Sequences of Dendralenes
por: Fan, Yi‐Min, et al.
Publicado: (2022)

How Bases Catalyze Diels‐Alder Reactions
por: Yu, Song, et al.
Publicado: (2022)

A chiral cobalt(ii) complex catalyzed enantioselective aza-Piancatelli rearrangement/Diels–Alder cascade reaction
por: Shen, Bin, et al.
Publicado: (2020)

Asymmetric synthesis of a highly functionalized bicyclo[3.2.2]nonene derivative
por: Tabuchi, Toshiki, et al.
Publicado: (2013)

A Direct Route to 6,6’-Disubstituted-2,2’-Bipyridines by Double Diels-Alder/retro Diels-Alder Reaction of 5,5’-bi-1,2,4-Triazines†
por: Branowska, Danuta
Publicado: (2005)

Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels–Alder Reactions
por: Sen, Rickdeb, et al.
Publicado: (2017)

Chitosan Hydrogels Based on the Diels–Alder Click Reaction: Rheological and Kinetic Study
por: Ruiz-Pardo, Cinthya, et al.
Publicado: (2022)

Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene
por: Ghosh, Santanu, et al.
Publicado: (2020)

Catalytic asymmetric multiple dearomatizations of phenols enabled by a cascade 1,8-addition and Diels–Alder reaction
por: Liu, Xihong, et al.
Publicado: (2019)

High stereoselectivity on low temperature Diels-Alder reactions
por: da Silva Filho, Luiz Carlos, et al.
Publicado: (2005)

Acylammonium Salts as Dienophiles in Diels–Alder/Lactonization Organocascades
por: Abbasov, Mikail E., et al.
Publicado: (2014)

How Lewis Acids Catalyze Diels–Alder Reactions
por: Vermeeren, Pascal, et al.
Publicado: (2020)

A versatile Diels–Alder approach to functionalized hydroanthraquinones
por: Beck, Janina, et al.
Publicado: (2020)

Dual-Wavelength Gated oxo-Diels–Alder Photoligation
por: Villabona, Marc, et al.
Publicado: (2021)

Alkylhalovinylboranes: a new class of Diels–Alder dienophiles
por: Pisano, Pablo L., et al.
Publicado: (2018)

Cross-Linking of Polypropylene via the Diels–Alder Reaction
por: Muljana, Henky, et al.
Publicado: (2022)

Radical cation Diels–Alder reactions of arylidene cycloalkanes
por: Nakayama, Kaii, et al.
Publicado: (2022)

Ultramicroporous Polyphenylenes via Diels–Alder Polycondensation Approach
por: Sorokina, Svetlana A., et al.
Publicado: (2023)

Base-promoted cascade β-F-elimination/electrocyclization/Diels–Alder/retro-Diels–Alder reaction: efficient access to δ-carboline derivatives
por: Sun, Xi-Shang, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_la6kb4m39ahuqa0jfdokm8df5p