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Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances

In order to solve the problem of poor compatibility between modified-ZIF-8 nanoparticles and mask matrix polypropylene (PP) and melt-blown materials, in this work, PP based modified-ZIF-8 antibacterial masterbatch was prepared employing surface modification and torque blending method. IR, SEM, XRD,...

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Detalles Bibliográficos
Autores principales: Zhang, Qian, Qiao, Qikai, Wang, Zihao, Liu, Yuanyuan, Pei, Zhen, Guo, Jiandong, Fei, Pengfei, Zhang, Aiqin, Jia, Husheng, Xu, Bingshe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9937522/
https://www.ncbi.nlm.nih.gov/pubmed/36844785
http://dx.doi.org/10.1007/s10904-023-02576-1
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author Zhang, Qian
Qiao, Qikai
Wang, Zihao
Liu, Yuanyuan
Pei, Zhen
Guo, Jiandong
Fei, Pengfei
Zhang, Aiqin
Jia, Husheng
Xu, Bingshe
author_facet Zhang, Qian
Qiao, Qikai
Wang, Zihao
Liu, Yuanyuan
Pei, Zhen
Guo, Jiandong
Fei, Pengfei
Zhang, Aiqin
Jia, Husheng
Xu, Bingshe
author_sort Zhang, Qian
collection PubMed
description In order to solve the problem of poor compatibility between modified-ZIF-8 nanoparticles and mask matrix polypropylene (PP) and melt-blown materials, in this work, PP based modified-ZIF-8 antibacterial masterbatch was prepared employing surface modification and torque blending method. IR, SEM, XRD, XPS, DSC results confirm that the antibacterial masterbatch maintains the chemical and crystal structure of modified-ZIF-8 and the thermal stability of PP. Photocatalytic performance indicates that the antibacterial masterbatch basically maintains the photoresponse range of modified-ZIF-8, has narrower band gap and the superior photocatalytic performance than that of modified-ZIF-8. The photocatalytic antibacterial mechanism of ·O(2)(−) and h(+) as antibacterial active species is revealed according to the energy band structure and free radical capture experiment. The photocatalytic antibacterial activity of the antibacterial masterbatch against Staphylococcus aureus and Escherichia coli under different dosage holds that the relationship between antibacterial rate and antibacterial agent concentration conforms to Beta distribution, demonstrating second-order kinetic behavior. The antibacterial properties reach the maximum when the loading of modified-ZIF-8 is 2% of the total weight of PP and melt-blown materials. S. aureus and E. coli could be completely killed when the simulated sunlight is irradiated for 30 min. These results indicate that PP based modified-ZIF-8 antibacterial masterbatch has potential application in photocatalytic antibacterial masks.
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spelling pubmed-99375222023-02-21 Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances Zhang, Qian Qiao, Qikai Wang, Zihao Liu, Yuanyuan Pei, Zhen Guo, Jiandong Fei, Pengfei Zhang, Aiqin Jia, Husheng Xu, Bingshe J Inorg Organomet Polym Mater Research In order to solve the problem of poor compatibility between modified-ZIF-8 nanoparticles and mask matrix polypropylene (PP) and melt-blown materials, in this work, PP based modified-ZIF-8 antibacterial masterbatch was prepared employing surface modification and torque blending method. IR, SEM, XRD, XPS, DSC results confirm that the antibacterial masterbatch maintains the chemical and crystal structure of modified-ZIF-8 and the thermal stability of PP. Photocatalytic performance indicates that the antibacterial masterbatch basically maintains the photoresponse range of modified-ZIF-8, has narrower band gap and the superior photocatalytic performance than that of modified-ZIF-8. The photocatalytic antibacterial mechanism of ·O(2)(−) and h(+) as antibacterial active species is revealed according to the energy band structure and free radical capture experiment. The photocatalytic antibacterial activity of the antibacterial masterbatch against Staphylococcus aureus and Escherichia coli under different dosage holds that the relationship between antibacterial rate and antibacterial agent concentration conforms to Beta distribution, demonstrating second-order kinetic behavior. The antibacterial properties reach the maximum when the loading of modified-ZIF-8 is 2% of the total weight of PP and melt-blown materials. S. aureus and E. coli could be completely killed when the simulated sunlight is irradiated for 30 min. These results indicate that PP based modified-ZIF-8 antibacterial masterbatch has potential application in photocatalytic antibacterial masks. Springer US 2023-02-17 2023 /pmc/articles/PMC9937522/ /pubmed/36844785 http://dx.doi.org/10.1007/s10904-023-02576-1 Text en © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. This article is made available via the PMC Open Access Subset for unrestricted research re-use and secondary analysis in any form or by any means with acknowledgement of the original source. These permissions are granted for the duration of the World Health Organization (WHO) declaration of COVID-19 as a global pandemic.
spellingShingle Research
Zhang, Qian
Qiao, Qikai
Wang, Zihao
Liu, Yuanyuan
Pei, Zhen
Guo, Jiandong
Fei, Pengfei
Zhang, Aiqin
Jia, Husheng
Xu, Bingshe
Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances
title Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances
title_full Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances
title_fullStr Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances
title_full_unstemmed Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances
title_short Covalent Bonding Enhanced Polypropylene Based T-ZIF-8 Masterbatch with Superior Photocatalytic and Antibacterial Performances
title_sort covalent bonding enhanced polypropylene based t-zif-8 masterbatch with superior photocatalytic and antibacterial performances
topic Research
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9937522/
https://www.ncbi.nlm.nih.gov/pubmed/36844785
http://dx.doi.org/10.1007/s10904-023-02576-1
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