From Small Metal Clusters to Molecular Nanoarchitectures with a Core–Shell Structure: The Synthesis, Redox Fingerprint, Theoretical Analysis, and Solid-State Structure of [Co(38)As(12)(CO)(50)](4–)

[Image: see text] The cluster [Co(38)As(12)(CO)(50)](4–) was obtained by pyrolysis of [Co(6)As(CO)(16)](−). The metal cage features a closed-packed core inside a Co/As shell that progressively deforms from a cubic face-centered symmetry. The redox and acid–base reactivities were determined by cyclic...

Descripción completa

Detalles Bibliográficos
Autores principales: Della Pergola, Roberto, Garlaschelli, Luigi, Macchi, Piero, Facchinetti, Irene, Ruffo, Riccardo, Racioppi, Stefano, Sironi, Angelo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9937531/
https://www.ncbi.nlm.nih.gov/pubmed/35731613
http://dx.doi.org/10.1021/acs.inorgchem.2c00506

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9937531/
https://www.ncbi.nlm.nih.gov/pubmed/35731613
http://dx.doi.org/10.1021/acs.inorgchem.2c00506

Ejemplares similares