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From Small Metal Clusters to Molecular Nanoarchitectures with a Core–Shell Structure: The Synthesis, Redox Fingerprint, Theoretical Analysis, and Solid-State Structure of [Co(38)As(12)(CO)(50)](4–)
[Image: see text] The cluster [Co(38)As(12)(CO)(50)](4–) was obtained by pyrolysis of [Co(6)As(CO)(16)](−). The metal cage features a closed-packed core inside a Co/As shell that progressively deforms from a cubic face-centered symmetry. The redox and acid–base reactivities were determined by cyclic...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9937531/ https://www.ncbi.nlm.nih.gov/pubmed/35731613 http://dx.doi.org/10.1021/acs.inorgchem.2c00506 |