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Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices

[Image: see text] Incorporating an intentional strain compensating InSb interface (IF) layer in InAs/GaSb type-II superlattices (T2SLs) enhances device performance. But there is a lack of studies that correlate this approach’s optical and structural quality, so the mechanisms by which this improveme...

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Autores principales: Alshahrani, Dhafer, Kesaria, Manoj, Jiménez, Juan J., Kwan, Dominic, Srivastava, Vibha, Delmas, Marie, Morales, Francisco M., Liang, Baolai, Huffaker, Diana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9940107/
https://www.ncbi.nlm.nih.gov/pubmed/36724387
http://dx.doi.org/10.1021/acsami.2c19292
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author Alshahrani, Dhafer
Kesaria, Manoj
Jiménez, Juan J.
Kwan, Dominic
Srivastava, Vibha
Delmas, Marie
Morales, Francisco M.
Liang, Baolai
Huffaker, Diana
author_facet Alshahrani, Dhafer
Kesaria, Manoj
Jiménez, Juan J.
Kwan, Dominic
Srivastava, Vibha
Delmas, Marie
Morales, Francisco M.
Liang, Baolai
Huffaker, Diana
author_sort Alshahrani, Dhafer
collection PubMed
description [Image: see text] Incorporating an intentional strain compensating InSb interface (IF) layer in InAs/GaSb type-II superlattices (T2SLs) enhances device performance. But there is a lack of studies that correlate this approach’s optical and structural quality, so the mechanisms by which this improvement is achieved remain unclear. One critical issue in increasing the performance of InAs/GaSb T2SLs arises from the lattice mismatch between InAs and GaSb, leading to interfacial strain in the structure. Not only that but also, since each side of the InAs/GaSb heterosystem does not have common atoms, there is a possibility of atomic intermixing at the IFs. To address such issues, an intentional InSb interfacial layer is commonly introduced at the InAs-on-GaSb and GaSb-on-InAs IFs to compensate for the strain and the chemical mismatches. In this report, we investigate InAs/GaSb T2SLs with (Sample A) and without (Sample B) InSb IF layers emitting in the mid-wavelength infrared (MWIR) through photoluminescence (PL) and band structure simulations. The PL studies indicate that the maximum PL intensity of Sample A is 1.6 times stronger than that of Sample B. This could be attributed to the effect of migration-enhanced epitaxy (MEE) growth mode. Band structure simulations understand the impact of atomic intermixing and segregation at T2SL IFs on the bandgap energy and PL intensity. It is observed that atomic intermixing at the IFs changes the bandgap energy and significantly affects the wave function overlap and the optical property of the samples. Transmission electron microscopy (TEM) measurements reveal that the T2SL IFs in Sample A are very rough compared to sharp IFs in Sample B, indicating a high possibility of atomic intermixing and segregation. Based on these results, it is believed that high-quality heterostructure could be achieved by controlling the IFs to enhance its structural and compositional homogeneities and the optical properties of the T2SLs.
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spelling pubmed-99401072023-02-21 Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices Alshahrani, Dhafer Kesaria, Manoj Jiménez, Juan J. Kwan, Dominic Srivastava, Vibha Delmas, Marie Morales, Francisco M. Liang, Baolai Huffaker, Diana ACS Appl Mater Interfaces [Image: see text] Incorporating an intentional strain compensating InSb interface (IF) layer in InAs/GaSb type-II superlattices (T2SLs) enhances device performance. But there is a lack of studies that correlate this approach’s optical and structural quality, so the mechanisms by which this improvement is achieved remain unclear. One critical issue in increasing the performance of InAs/GaSb T2SLs arises from the lattice mismatch between InAs and GaSb, leading to interfacial strain in the structure. Not only that but also, since each side of the InAs/GaSb heterosystem does not have common atoms, there is a possibility of atomic intermixing at the IFs. To address such issues, an intentional InSb interfacial layer is commonly introduced at the InAs-on-GaSb and GaSb-on-InAs IFs to compensate for the strain and the chemical mismatches. In this report, we investigate InAs/GaSb T2SLs with (Sample A) and without (Sample B) InSb IF layers emitting in the mid-wavelength infrared (MWIR) through photoluminescence (PL) and band structure simulations. The PL studies indicate that the maximum PL intensity of Sample A is 1.6 times stronger than that of Sample B. This could be attributed to the effect of migration-enhanced epitaxy (MEE) growth mode. Band structure simulations understand the impact of atomic intermixing and segregation at T2SL IFs on the bandgap energy and PL intensity. It is observed that atomic intermixing at the IFs changes the bandgap energy and significantly affects the wave function overlap and the optical property of the samples. Transmission electron microscopy (TEM) measurements reveal that the T2SL IFs in Sample A are very rough compared to sharp IFs in Sample B, indicating a high possibility of atomic intermixing and segregation. Based on these results, it is believed that high-quality heterostructure could be achieved by controlling the IFs to enhance its structural and compositional homogeneities and the optical properties of the T2SLs. American Chemical Society 2023-02-01 /pmc/articles/PMC9940107/ /pubmed/36724387 http://dx.doi.org/10.1021/acsami.2c19292 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Alshahrani, Dhafer
Kesaria, Manoj
Jiménez, Juan J.
Kwan, Dominic
Srivastava, Vibha
Delmas, Marie
Morales, Francisco M.
Liang, Baolai
Huffaker, Diana
Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices
title Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices
title_full Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices
title_fullStr Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices
title_full_unstemmed Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices
title_short Effect of Interfacial Schemes on the Optical and Structural Properties of InAs/GaSb Type-II Superlattices
title_sort effect of interfacial schemes on the optical and structural properties of inas/gasb type-ii superlattices
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9940107/
https://www.ncbi.nlm.nih.gov/pubmed/36724387
http://dx.doi.org/10.1021/acsami.2c19292
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