Immobilized Cu(0) nanoparticles on montmorillonite-modified with benzalkonium chloride (MMT-BAC@Cu(0)): as an eco-friendly and proficient heterogeneous nano-catalyst for green synthesis of 5-substituted 1H-tetrazoles

In this study, Cu(0) nanoparticles supported on organo-modified montmorillonite with benzalkonium chloride (MMT-BAC@Cu(0)) were synthesized and used as an eco-friendly and green heterogeneous catalyst for the synthesis of 5-substituted 1H-tetrazoles in mild media. The structure of the catalyst was investigated using various techniques including XRD, EDX, ICP, TEM, FE-SEM, and FT-IR. The advantages of availability, low cost, non-toxicity, and biocompatibility of clay were our focus in synthesizing this nanoclay catalyst. The method's advantages include good to excellent product yields, mild conditions, easy work-up, short reaction times, and easy reuse of the nanocatalyst.