Multifunctional screen-printed films using polymer nanocomposite based on PPy/TiO(2): conductive, photocatalytic, self-cleaning and antibacterial functionalities

In this work, two electrically conductive samples based on polypyrrole (PPy) and (PPy/TiO(2)) were synthesized via mini-emulsion polymerization. Synthesized samples were used as functional fillers to formulate two different screen-printing pastes (pastes A and B) to obtain the multi-purpose printed films with excellent properties, including electrical conductivity, antibacterial, photocatalytic activity, and self-cleaning. The surface tension, pH, and conductivity measurements validated the acceptable features of the produced pastes. Because of the shear-thinning behavior and viscosity buildup properties of the produced pastes, rheological investigations confirmed their potential for screen-printing. According to I–V test results, the optimum sintering temperature was chosen as a function of electrical conductivity, and the properties of the printed patterns were investigated by varying the printing sequences as 3, 6, and 9 times and sintered at the optimum temperature (90 °C). The contact angle of water on the optimum sample printed by Paste B was ca. 127° and relatively higher than the counterpart printed by Paste A which verified the superiority of the self-cleaning properties of the printed films with latter paste over the former. The photocatalytic studies concerning the degradation of methylene blue showed that the removal percentage of ca. 63% was achieved within the first 90 min of performing the test under UV light. The photocatalytic printed film was addressed the issue of filtering the unused suspension of nanoparticles, which made it difficult to remove the particles from the treated wastewater, in terms of sustainability. The fabricated patterns using Paste B exhibited improved properties, including electrical conductivity, antibacterial and photocatalytic activity. GRAPHICAL ABSTRACT: [Image: see text]