Organocatalyzed enantio- and diastereoselective isomerization of prochiral 1,3-cyclohexanediones into nonalactones bearing distant stereocenters

The lactonization of 2-(2-nitrophenyl)-1,3-cyclohexanediones containing an alcohol side chain and up to three distant prochiral elements is reported by isomerization under the mediation of simple organocatalysts such as quinidine. Through a process of ring expansion, strained nonalactones and decala...

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Detalles Bibliográficos
Autores principales: d’Aleman, Antoine, Gayraud, Oscar, Fressigné, Catherine, Petit, Emilie, Bailly, Laetitia, Maddaluno, Jacques, De Paolis, Michaël
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945243/
https://www.ncbi.nlm.nih.gov/pubmed/36845928
http://dx.doi.org/10.1039/d2sc06842g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945243/
https://www.ncbi.nlm.nih.gov/pubmed/36845928
http://dx.doi.org/10.1039/d2sc06842g

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