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A syn outer-sphere oxidative addition: the reaction mechanism in Pd/Senphos-catalyzed carboboration of 1,3-enynes

We report a combined experimental and computational study of Pd/Senphos-catalyzed carboboration of 1,3-enynes utilizing DFT calculations, (31)P NMR study, kinetic study, Hammett analysis and Arrhenius/Eyring analysis. Our mechanistic study provides evidence against the conventional inner-sphere β-mi...

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Detalles Bibliográficos
Autores principales: Wang, Ziyong, Lamine, Walid, Miqueu, Karinne, Liu, Shih-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945512/
https://www.ncbi.nlm.nih.gov/pubmed/36845936
http://dx.doi.org/10.1039/d2sc05828f

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