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Molecular cyclo-P(3) complexes of the rare-earth elements via a one-pot reaction and selective reduction

Synthesis of new organo-lanthanide polyphosphides with an aromatic cyclo-[P(4)](2−) moiety and a cyclo-[P(3)](3−) moiety is presented. For this purpose, the divalent Ln(II)-complexes [(NON)Ln(II)(thf)(2)] (Ln = Sm, Yb) ((NON)(2−) = 4,5-bis(2,6-diisopropylphenyl-amino)-2,7-di-tert-butyl-9,9-dimethylx...

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Detalles Bibliográficos
Autores principales:	Hauser, Adrian, Münzfeld, Luca, Schlittenhardt, Sören, Köppe, Ralf, Uhlmann, Cedric, Rauska, Ulf-Christian, Ruben, Mario, Roesky, Peter W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945584/ https://www.ncbi.nlm.nih.gov/pubmed/36845933 http://dx.doi.org/10.1039/d2sc06730g

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