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Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution

[Image: see text] In this paper, Er(3+)/Yb(3+) codoped Y(2(1–x%))Lu(2x %)O(3) solid solution was prepared through the sol–gel method, and the substitution of Y(3+) by Lu(3+) ions in Y(2)O(3) was confirmed by X-ray diffraction data. The up-conversion emissions of samples under 980 nm excitation and t...

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Autores principales: Hao, Haoyue, Zhu, MengYao, Li, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9948156/
https://www.ncbi.nlm.nih.gov/pubmed/36844592
http://dx.doi.org/10.1021/acsomega.2c07565
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author Hao, Haoyue
Zhu, MengYao
Li, Liang
author_facet Hao, Haoyue
Zhu, MengYao
Li, Liang
author_sort Hao, Haoyue
collection PubMed
description [Image: see text] In this paper, Er(3+)/Yb(3+) codoped Y(2(1–x%))Lu(2x %)O(3) solid solution was prepared through the sol–gel method, and the substitution of Y(3+) by Lu(3+) ions in Y(2)O(3) was confirmed by X-ray diffraction data. The up-conversion emissions of samples under 980 nm excitation and the relative up-conversion processes are investigated. The emission shapes do not vary with the change in doping concentration due to the unaltered cubic phase. The red-to-green ratio changes from 2.7 to 7.8 and then declines to 4.4 as the doping concentration of Lu(3+) increases from 0 to 100. The emission lifetimes of green and red have similar variation: the emission lifetime decreases with doping concentration changing from 0 to 60 and rises as the doping concentration continues to increase. The reason why the emission ratio and lifetime change could be originated to the exacerbation of cross-relaxing process and the change of radiative transition probabilities. The temperature-dependent fluorescence intensity ratio (FIR) shows that all samples can be used in noncontact optical temperature sensing, and the method of local structure distortion can be used to improve sensitivity further. The max sensing sensitivities of FIR based on R(538/563) and R(red/green) reach 0.011 K(–1) (483 K) and 0.21 K(–1) (300 K). The results display that Er(3+)/Yb(3+) codoped Y(2(1–x %))Lu(2x %)O(3) solid solution can be potential candidates for optical temperature sensing in different temperature ranges.
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spelling pubmed-99481562023-02-24 Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution Hao, Haoyue Zhu, MengYao Li, Liang ACS Omega [Image: see text] In this paper, Er(3+)/Yb(3+) codoped Y(2(1–x%))Lu(2x %)O(3) solid solution was prepared through the sol–gel method, and the substitution of Y(3+) by Lu(3+) ions in Y(2)O(3) was confirmed by X-ray diffraction data. The up-conversion emissions of samples under 980 nm excitation and the relative up-conversion processes are investigated. The emission shapes do not vary with the change in doping concentration due to the unaltered cubic phase. The red-to-green ratio changes from 2.7 to 7.8 and then declines to 4.4 as the doping concentration of Lu(3+) increases from 0 to 100. The emission lifetimes of green and red have similar variation: the emission lifetime decreases with doping concentration changing from 0 to 60 and rises as the doping concentration continues to increase. The reason why the emission ratio and lifetime change could be originated to the exacerbation of cross-relaxing process and the change of radiative transition probabilities. The temperature-dependent fluorescence intensity ratio (FIR) shows that all samples can be used in noncontact optical temperature sensing, and the method of local structure distortion can be used to improve sensitivity further. The max sensing sensitivities of FIR based on R(538/563) and R(red/green) reach 0.011 K(–1) (483 K) and 0.21 K(–1) (300 K). The results display that Er(3+)/Yb(3+) codoped Y(2(1–x %))Lu(2x %)O(3) solid solution can be potential candidates for optical temperature sensing in different temperature ranges. American Chemical Society 2023-02-07 /pmc/articles/PMC9948156/ /pubmed/36844592 http://dx.doi.org/10.1021/acsomega.2c07565 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Hao, Haoyue
Zhu, MengYao
Li, Liang
Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution
title Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution
title_full Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution
title_fullStr Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution
title_full_unstemmed Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution
title_short Up-Conversion Luminescence and Temperature Sensing of Er(3+)/Yb(3+) Codoped Y(2(1–x %))Lu(2x %)O(3) Solid Solution
title_sort up-conversion luminescence and temperature sensing of er(3+)/yb(3+) codoped y(2(1–x %))lu(2x %)o(3) solid solution
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9948156/
https://www.ncbi.nlm.nih.gov/pubmed/36844592
http://dx.doi.org/10.1021/acsomega.2c07565
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