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Stereo- and Regiospecific S(N)2′ Reaction of MBH Adducts with Isocyanoacetates: en Route to Transition-Metal-Free α-Allylation of Isocyanoacetates
[Image: see text] Herein, we report that under mild and transition-metal-free conditions an unprecedented and practical S(N)2′ reaction of Morita–Baylis–Hillman adducts with isocyanoacetates takes place in a stereo- and regiospecific manner. This reaction which tolerates a wide variety of functional...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9948183/ https://www.ncbi.nlm.nih.gov/pubmed/36844594 http://dx.doi.org/10.1021/acsomega.2c07581 |