Computational Design of a Tetrapericyclic Cycloaddition and the Nature of Potential Energy Surfaces with Multiple Bifurcations

[Image: see text] An ambimodal transition state (TS) that leads to formation of four different pericyclic reaction products ([4 + 6]-, [2 + 8]-, [8 + 2]-, and [6 + 4]-cycloadducts) without any intervening minima has been designed and explored with DFT computations and quasiclassical molecular dynami...

Descripción completa

Detalles Bibliográficos
Autores principales: Martin-Somer, Ana, Xue, Xiao-Song, Jamieson, Cooper S., Zou, Yike, Houk, K.N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9951208/
https://www.ncbi.nlm.nih.gov/pubmed/36757329
http://dx.doi.org/10.1021/jacs.2c12871

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9951208/
https://www.ncbi.nlm.nih.gov/pubmed/36757329
http://dx.doi.org/10.1021/jacs.2c12871

Ejemplares similares