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Enantioselective Hydroalkoxylation of 1,3-Dienes via Ni-Catalysis

[Image: see text] As an advance in hydrofunctionalization, we herein report that alcohols add to 1,3-dienes with high regio- and enantioselectivity. Using Ni-DuPhos, we access enantioenriched allylic ethers. Through the choice of solvent-free conditions, we control the reversibility of C–O bond form...

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Detalles Bibliográficos
Autores principales: Li, Qi, Wang, Zhen, Dong, Vy M., Yang, Xiao-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9951252/
https://www.ncbi.nlm.nih.gov/pubmed/36763788
http://dx.doi.org/10.1021/jacs.2c12779